Thermostable Organo-phosphor: Low-Vibrational Coordination Polymers That Exhibit Different Intermolecular Interactions

Novel thermostable organo‐phosphor compounds composed of coordination polymers are reported. Tight‐binding structures with intermolecular interactions of the coordination polymer induce both thermostability (decomposition point >300 °C) and high emission quantum yield (ΦLn=83 %). Their structures...

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Bibliographic Details
Published in:ChemPlusChem (Weinheim, Germany) Germany), 2012-04, Vol.77 (4), p.277-280
Main Authors: Miyata, Kohei, Ohba, Tadashi, Kobayashi, Atsushi, Kato, Masako, Nakanishi, Takayuki, Fushimi, Koji, Hasegawa, Yasuchika
Format: Article
Language:English
Subjects:
coordination modes
coordination polymers
luminescence
metal-organic frameworks
phosphane ligands
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Summary:Novel thermostable organo‐phosphor compounds composed of coordination polymers are reported. Tight‐binding structures with intermolecular interactions of the coordination polymer induce both thermostability (decomposition point >300 °C) and high emission quantum yield (ΦLn=83 %). Their structures (see picture), thermogravimetric analyses, and remarkable photophysical properties are presented for the first time.
ISSN:2192-6506
2192-6506
DOI:10.1002/cplu.201200002