An Easy Route to Monofunctionalized Organoimido Derivatives of the Lindqvist Hexamolybdate

In the presence of a carbodiimide (DCC) a proton can dramatically speed up the reaction of α‐[Mo8O26]4− with aromatic amines under mild conditions and convenient bench manipulations, which results in the easy synthesis of monofunctionalized organoimido derivatives of [Mo6O19]2− even bearing an elect...

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Bibliographic Details
Published in:European journal of inorganic chemistry 2004-07, Vol.2004 (14), p.2819-2822
Main Authors: Wu, Pingfan, Li, Qiang, Ge, Ning, Wei, Yongge, Wang, Yuan, Wang, Ping, Guo, Hongyou
Format: Article
Language:English
Subjects:
Acid Catalysis
Dehydration
Organic−inorganic hybrid
Organoimido Derivatives
Polyoxometalates
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Summary:In the presence of a carbodiimide (DCC) a proton can dramatically speed up the reaction of α‐[Mo8O26]4− with aromatic amines under mild conditions and convenient bench manipulations, which results in the easy synthesis of monofunctionalized organoimido derivatives of [Mo6O19]2− even bearing an electron‐withdrawing group such as bromo or chloro groups. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
ISSN:1434-1948
1099-0682
DOI:10.1002/ejic.200400168