Low-Valent Titanium−Pentafulvene Complexes − Formation of Dinuclear Titanium−Nitrogen Complexes (Eur. J. Inorg. Chem. 6/2005)

The cover picture shows a high‐yield, one‐step synthesis of end‐on bridged dinuclear titanium−dinitrogen complexes using Cp*TiCl3, N2 and pentafulvenes under reductive conditions. The Cp* as well as the fulvene ligands are arranged in a stereoregular manner along the Ti−N≡N−Ti axis, both in the soli...

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Bibliographic Details
Published in:European journal of inorganic chemistry 2005-03, Vol.2005 (6), p.989-989
Main Authors: Scherer, Axel, Kollak, Kay, Lützen, Arne, Friedemann, Marion, Haase, Detlev, Saak, Wolfgang, Beckhaus, Rüdiger
Format: Article
Language:English
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Summary:The cover picture shows a high‐yield, one‐step synthesis of end‐on bridged dinuclear titanium−dinitrogen complexes using Cp*TiCl3, N2 and pentafulvenes under reductive conditions. The Cp* as well as the fulvene ligands are arranged in a stereoregular manner along the Ti−N≡N−Ti axis, both in the solid state as well as in solution, as proved by extensive NMR measurements. Details are discussed in the article by R. Beckhaus et al. on p. 1003 ff. In a similar way a nitrogen‐free, low‐coordinated titanium complex is obtained by using sterically demanding benzofulvenes. We thank the Fonds der Chemischen Industrie for a kindly granted scholarship (A. S.).
ISSN:1434-1948
1099-0682
DOI:10.1002/ejic.200590012