Reactions of Trimethylphosphane-Supported Cobalt Complexes with Salicylaldimines - Formation and Structures of Cobalt Compounds Containing Salicylaldiminato [N:O] Ligands

The reactions of low‐valent cobalt complexes CoMe(PMe3)4, CoCl(PMe3)3 and Co(PMe3)4 with salicylaldimines are described to give tetrahedral complexes 7–12, an octahedral complex 13 and a π‐coordinated imine complex 15. The crystal structures of 13 and 15 are reported. The formation and likely mechan...

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Bibliographic Details
Published in:European Journal of Inorganic Chemistry 2006-11, Vol.2006 (21), p.4362-4367
Main Authors: Li, Xiaoyan, Yu, Fengli, Sun, Hongjian, Huang, Liye, Hou, Haoqing
Format: Article
Language:English
Subjects:
Cobalt
Imines
Salicylaldimines
Trimethylphosphane
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Summary:The reactions of low‐valent cobalt complexes CoMe(PMe3)4, CoCl(PMe3)3 and Co(PMe3)4 with salicylaldimines are described to give tetrahedral complexes 7–12, an octahedral complex 13 and a π‐coordinated imine complex 15. The crystal structures of 13 and 15 are reported. The formation and likely mechanisms are discussed. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
ISSN:1434-1948
1099-0682
DOI:10.1002/ejic.200600489