K 3 [ M O 4 ][ M O 3 N] ( M =Tc, Re) – Nitridotrioxidorhenate and ‐technetate from Highly Alkaline Media

The reactions of ammonium perrhenate and pertechnetate in highly alkaline medium led to the isotypic mixed anionic nitridotrioxidorhenate and ‐technetate K 3 [ M O 4 ][ M O 3 N] ( M = Tc, Re). Both compounds occur as colorless crystals, which were investigated by single crystal X‐ray diffraction. Fu...

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Bibliographic Details
Published in:European journal of inorganic chemistry 2023-09, Vol.26 (26)
Main Authors: Badea, Désirée, Olthof, Selina, Neudörfl, Jörg M., Glaum, Robert, Pöttgen, Rainer, Reimann, Maximilian Kai, Meerholz, Klaus, Reimer, Max, Logemann, Christian, Strub, Erik, Bruns, Jörn
Format: Article
Language:English
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Summary:The reactions of ammonium perrhenate and pertechnetate in highly alkaline medium led to the isotypic mixed anionic nitridotrioxidorhenate and ‐technetate K 3 [ M O 4 ][ M O 3 N] ( M = Tc, Re). Both compounds occur as colorless crystals, which were investigated by single crystal X‐ray diffraction. Furthermore, K 3 [ReO 4 ][ReO 3 N] has been studied by means of X‐ray photoelectron spectroscopy to determine the oxidation state of rhenium. The obtained results have been complemented by magnetic measurements. IR and Raman spectroscopy indicated the presence of Re−O as well as Re−N bonds.
ISSN:1434-1948
1099-0682
DOI:10.1002/ejic.202300160