Organolead-Mediated Arylations: 2-(3,3-Diphenylallyloxy)phenyllead Triacetate as an Internal Free-Radical-Trap-Containing Reagent

2‐(3,3‐Diphenylprop‐2‐enyloxy)phenyllead triacetate, an arylating reagent containing an internal free radical trap, was synthesised and its behaviour studied in base‐catalysed C‐arylation reactions and in copper‐catalysed N‐arylation reactions. The absence of benzofuran derivatives among the product...

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Bibliographic Details
Published in:European journal of organic chemistry 2004-05, Vol.2004 (9), p.2040-2045
Main Authors: Fedorov, Alexey Yu. , Finet, Jean-Pierre
Format: Article
Language:English
Subjects:
Arylation
Copper
Organolead
Radical trap
Radicals
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Summary:2‐(3,3‐Diphenylprop‐2‐enyloxy)phenyllead triacetate, an arylating reagent containing an internal free radical trap, was synthesised and its behaviour studied in base‐catalysed C‐arylation reactions and in copper‐catalysed N‐arylation reactions. The absence of benzofuran derivatives among the products of C‐ and N‐arylation reactions excludes the involvement of radical species in these two processes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.200300784