Stereoselective Chloro-Deboronation Reactions Induced by Substituted Pyridine-Iodine Chloride Complexes

A novel class of charge‐transfer complexes based on iodine chloride and substituted pyridines, which possess a number of interesting and unique structural features, can be employed to bring about a stereocontrolled chloro‐deboronation of certain vinyl boronates to generate the (1Z)‐alkenyl chlorides...

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Bibliographic Details
Published in:European Journal of Organic Chemistry 2005-05, Vol.2005 (9), p.1876-1883
Main Authors: Batsanov, Andrei S., Howard, Judith A. K., Lightfoot, Andrew P., Twiddle, Steven J. R., Whiting, Andrew
Format: Article
Language:English
Subjects:
Chloro-deboronation
Complexes
Iodine chloride
Iodo-deboronation
Pyridines
Vinylboronate
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Summary:A novel class of charge‐transfer complexes based on iodine chloride and substituted pyridines, which possess a number of interesting and unique structural features, can be employed to bring about a stereocontrolled chloro‐deboronation of certain vinyl boronates to generate the (1Z)‐alkenyl chlorides in good yields. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.200400855