Enantioselective Synthesis of Thiosulfinates and of Acyclic Alkylidenemethylene Sulfide Sulfoxides

Enantioselectivities up to 75 % have been found in the catalytic mono‐oxidation of di‐tert‐butyl disulfide and related compounds as well as of ketene‐S,S‐acetals with an in situ generated chiral dioxirane. The effect of solvents on the enantiomeric excess has also been examined. (© Wiley‐VCH Verlag...

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Bibliographic Details
Published in:European Journal of Organic Chemistry 2005-05, Vol.2005 (9), p.1727-1730
Main Authors: Colonna, Stefano, Pironti, Vincenza, Drabowicz, Jozef, Brebion, Franck, Fensterbank, Louis, Malacria, Max
Format: Article
Language:English
Subjects:
Asymmetric synthesis
Bovine serum albumin
Chiral dioxirane
Enantioselectivity
Thiosulfinate
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Summary:Enantioselectivities up to 75 % have been found in the catalytic mono‐oxidation of di‐tert‐butyl disulfide and related compounds as well as of ketene‐S,S‐acetals with an in situ generated chiral dioxirane. The effect of solvents on the enantiomeric excess has also been examined. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.200400892