Synthesis of Pulvinic Acid and Norbadione A Analogues by Suzuki-Miyaura Cross-Coupling of Benzylated Intermediates

Pulvinic acid and norbadione A analogues can be prepared by Suzuki–Miyaura cross‐coupling of functionalized arylboronic esters with appropriate vinyl triflates, in which the hydroxy functions are protected either with methyl or benzyl groups, the latter being cleaved in a more reliable fashion at th...

Full description

Saved in:
Bibliographic Details
Published in:European Journal of Organic Chemistry 2006-03, Vol.2006 (6), p.1489-1498
Main Authors: Desage-El Murr, Marine, Nowaczyk, Stéphanie, Le Gall, Thierry, Mioskowski, Charles
Format: Article
Language:English
Subjects:
Boronic esters
Cross-coupling
Heterocycles
Natural products
Synthetic methods
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Pulvinic acid and norbadione A analogues can be prepared by Suzuki–Miyaura cross‐coupling of functionalized arylboronic esters with appropriate vinyl triflates, in which the hydroxy functions are protected either with methyl or benzyl groups, the latter being cleaved in a more reliable fashion at the end of the synthetic sequence. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.200500837