Synthesis and Substitution of 8-(4,6-Dichloropyrimidin-5-yl)-BODIPY

meso‐Dichloropyrimidyl‐BODIPY dyes are readily substituted by nucleophiles or through palladium‐catalysed coupling reactions, while retaining excellent quantum yields of fluorescence. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009) The facile synthesis of dichloropyrimidinyl‐...

Full description

Saved in:
Bibliographic Details
Published in:European Journal of Organic Chemistry 2009-12, Vol.2009 (34), p.5920-5926
Main Authors: Leen, Volker, Schevenels, Florian, Cui, Jie, Xu, Chan, Yang, Wensheng, Tang, Xiaoliang, Liu, Weisheng, Qin, Wenwu, De Borggraeve, Wim M., Boens, Noël, Dehaen, Wim
Format: Article
Language:English
Subjects:
Chemistry
Dyes/pigments
Exact sciences and technology
Fluorescent probes
Heterocyclic compounds
Heterocyclic compounds with several n hetero atoms in the same ring, in separated rings or in fused rings
Miscellaneous
Nucleophilic substitution
Organic chemistry
Palladium-catalysed reactions
Preparations and properties
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:meso‐Dichloropyrimidyl‐BODIPY dyes are readily substituted by nucleophiles or through palladium‐catalysed coupling reactions, while retaining excellent quantum yields of fluorescence. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009) The facile synthesis of dichloropyrimidinyl‐BODIPY dyes is reported. These dyes show excellent reactivity towards nucleophilic aromatic substitution and transition‐metal‐catalysed reactions, while retaining outstanding spectroscopic properties.
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.200900722