Cover Feature: Nickel‐Catalyzed Synthesis of Diaryl Sulfones from Aryl Halides and Sodium Sulfinates (Eur. J. Org. Chem. 10/2018)

The Cover Feature shows the first nickel‐catalyzed cross‐coupling of sodium sulfinates with aryl bromides. This method enables a straightforward synthesis of diarylsulfones with high functional group compatibility. The active nickel‐catalyst is generated in situ from the nickel(II) precursor NiBr2,...

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Bibliographic Details
Published in:European journal of organic chemistry 2018-03, Vol.2018 (10), p.1175-1175
Main Authors: Liu, Nai‐Wei, Liang, Shuai, Margraf, Natalie, Shaaban, Saad, Luciano, Vanessa, Drost, Marcella, Manolikakes, Georg
Format: Article
Language:English
Online Access:Get full text
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Summary:The Cover Feature shows the first nickel‐catalyzed cross‐coupling of sodium sulfinates with aryl bromides. This method enables a straightforward synthesis of diarylsulfones with high functional group compatibility. The active nickel‐catalyst is generated in situ from the nickel(II) precursor NiBr2, an N‐heterocyclic carbene ligand, and triethylsilane as reducing agent. More information can be found in the Communication by G. Manolikakes et al.
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.201800174