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Unexpected Novel Pheophytin Peroxides from the Leaves of Biden pilosa
Two new pheophytins, bidenphytins A (1) and B (2), with peroxide functionalities on ring E, were isolated from Biden pilosa Linn. var. radiata Sch. Bip., a popular Taiwanese folk medicine. Also isolated were the following six known compounds: pheophytin a (3), (132R)‐132‐hydroxypheophytin a (4), (13...
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Published in: | Helvetica chimica acta 2008-01, Vol.91 (1), p.79-84 |
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Main Authors: | , , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Two new pheophytins, bidenphytins A (1) and B (2), with peroxide functionalities on ring E, were isolated from Biden pilosa Linn. var. radiata Sch. Bip., a popular Taiwanese folk medicine. Also isolated were the following six known compounds: pheophytin a (3), (132R)‐132‐hydroxypheophytin a (4), (132S)‐132‐hydroxypheophytin a (5), (132R)‐132‐hydroxypheophytin b (6), (132S)‐132‐hydroxypheophytin b (7), and aristophyll‐C (8). Their structures were elucidated by spectroscopic methods (UV, IR, 1D‐ and 2D‐NMR) and by mass spectrometry (HR‐FAB‐MS). Possible biosynthetic pathways for 1 and 2 are proposed. |
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ISSN: | 0018-019X 1522-2675 |
DOI: | 10.1002/hlca.200890016 |