Octanuclear Cu(I)-dithiophosphates: An Efficient Catalyst System for N-Arylation of Azoles, Amines, and Amides

The formation of a C‐N bond via the cross‐couplings of aryl iodides with azoles, aryl amine, and amides can be successfully achieved in decent yield by the utilization of both [Cu 8(H){S2P(OiPr)2}6]+ and [Cu8{S2P(OEt)2}6]2+ as the pre‐catalysts. C‐N bond formations via the cross‐couplings of aryl io...

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Bibliographic Details
Published in:Journal of the Chinese Chemical Society (Taipei) 2012-04, Vol.59 (4), p.480-484
Main Authors: Wu, Cheng-Chieh, Lee, Bo-Han, Liao, Ping-Kuei, Fang, Ching-Shiang, Liu, C. W.
Format: Article
Language:English
Subjects:
Copper
Cross-coupling
N-arylation
S-donor ligands
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Summary:The formation of a C‐N bond via the cross‐couplings of aryl iodides with azoles, aryl amine, and amides can be successfully achieved in decent yield by the utilization of both [Cu 8(H){S2P(OiPr)2}6]+ and [Cu8{S2P(OEt)2}6]2+ as the pre‐catalysts. C‐N bond formations via the cross‐couplings of aryl iodides with azoles, aryl amine, and amides can be achieved by the utilization of [Cu 8(H){S2P(OiPr)2}6]+ as the pre‐catalysts.
ISSN:0009-4536
2192-6549
DOI:10.1002/jccs.201100592