Quantitative synthesis and NMR characterization of perhydro-1,3,5-tris(alkylpolyalkoxyl)-S-triazines

Unhindered polyalkoxylated primary amines, upon treatment with an equimolar equivalent of formalde hyde, cyclized quantitatively to afford perhydro‐1,3,5‐s‐triazines. This sereis of derivatives, based upon primary amine terminated poly(propylene and butylene oxides), possessed a molecular weight ran...

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Bibliographic Details
Published in:Journal of heterocyclic chemistry 2000-09, Vol.37 (5), p.1157-1160
Main Authors: Wolak, Thomas J., Wollenberg, Kurt F., Adams, Paul E.
Format: Article
Language:English
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Summary:Unhindered polyalkoxylated primary amines, upon treatment with an equimolar equivalent of formalde hyde, cyclized quantitatively to afford perhydro‐1,3,5‐s‐triazines. This sereis of derivatives, based upon primary amine terminated poly(propylene and butylene oxides), possessed a molecular weight range of 1,900–5,800. Structure confirmation was accomplished by gel permeation chromatography and 2D nmr spectroscopy methods.
ISSN:0022-152X
1943-5193
DOI:10.1002/jhet.5570370522