Loading…

Raman characterizations and structural properties of the binary TeO 2 WO 3 , TeO 2 CdF 2 and ternary TeO 2 CdF 2 WO 3 glasses

The Raman spectroscopy technique was used to characterize the microstructure and the crystallization properties of the as‐cast and heat‐treated binary TeO 2 WO 3 , TeO 2 CdF 2 and ternary TeO 2 CdF 2 WO 3 glasses and glass ceramics. The results were compared with those obtained by using the X‐ra...

Full description

Saved in:
Bibliographic Details
Published in:Journal of Raman spectroscopy 2010-07, Vol.41 (7), p.797-807
Main Authors: Tatar, D., Özen, G., Erim, F. B., Öveçoǧlu, M. L.
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c729-e348df59c8f1cbe9d717158a668dcca4e74ead602b203fc6341faa8ed5f95daf3
cites cdi_FETCH-LOGICAL-c729-e348df59c8f1cbe9d717158a668dcca4e74ead602b203fc6341faa8ed5f95daf3
container_end_page 807
container_issue 7
container_start_page 797
container_title Journal of Raman spectroscopy
container_volume 41
creator Tatar, D.
Özen, G.
Erim, F. B.
Öveçoǧlu, M. L.
description The Raman spectroscopy technique was used to characterize the microstructure and the crystallization properties of the as‐cast and heat‐treated binary TeO 2 WO 3 , TeO 2 CdF 2 and ternary TeO 2 CdF 2 WO 3 glasses and glass ceramics. The results were compared with those obtained by using the X‐ray diffraction technique. The effect of the WO 3 and CdF 2 contents on the TeO 2 glass network and the intensity ratios of the deconvoluted Raman peaks were determined. The shifts in the Raman band wavenumbers and the intensity values for each band were investigated. The Raman results indicated that the glasses were mainly formed by the [TeO 4 ] and [TeO 3 ] units. The [TeO 4 ] units convert to [TeO 3 ] units with the addition of WO 3 and CdF 2 into tellurite glasses. All the crystalline phases such as α‐TeO 2 , δ‐TeO 2 and γ‐TeO 2 existing in the TeO 2 WO 3 , TeO 2 CdF 2 and TeO 2 ‐ WO 3 CdF 2 glasses were determined. The transformation of the metastable γ‐TeO 2 phase into stable α‐TeO 2 was observed for the (1 − x )TeO 2  x WO 3 (where x = 0.15, 0.20, 0.25), 0.90Te 2 0.10CdF 2 , the 0.85TeO 2 0.10CdF 2 0.05WO 3 and 0.80TeO 2 0.10CdF 2 0.10WO 3 glasses, and the transformation of the metastable δ‐TeO 2 phase into the stable α‐TeO 2 was also observed for the TeO 2 CdF 2 WO 3 glass system. In addition, an unidentified phase formation, labeled ε, was determined. Copyright © 2009 John Wiley & Sons, Ltd.
doi_str_mv 10.1002/jrs.2519
format article
fullrecord <record><control><sourceid>crossref</sourceid><recordid>TN_cdi_crossref_primary_10_1002_jrs_2519</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1002_jrs_2519</sourcerecordid><originalsourceid>FETCH-LOGICAL-c729-e348df59c8f1cbe9d717158a668dcca4e74ead602b203fc6341faa8ed5f95daf3</originalsourceid><addsrcrecordid>eNpVkMFKxDAQhoMoWFfBR8jRg12TpkmaoxRXhYUFWfBYpsnE7bLblqR70DfwOXwQH8lXsMsq4mlm-Gc-ho-QS86mnLHsZh3iNJPcHJGEM6PTXEp5TBImtE5ZXqhTchbjmjFmjOIJeX-CLbTUriCAHTA0bzA0XRsptI7GIezssAuwoX3oegxDg5F2ng4rpHXTQnilS1zQjH59fD4vqKDXf3PpZmOzx4zY_6uH6PfmZQMxYjwnJx42ES9-6oQsZ3fL8iGdL-4fy9t5anVmUhR54bw0tvDc1mic5prLApQqnLWQo84RnGJZnTHhrRI59wAFOumNdODFhFwdsDZ0MQb0VR-a7fhexVm1N1iNBqu9QfENqfJnxQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Raman characterizations and structural properties of the binary TeO 2 WO 3 , TeO 2 CdF 2 and ternary TeO 2 CdF 2 WO 3 glasses</title><source>Wiley:Jisc Collections:Wiley Read and Publish Open Access 2024-2025 (reading list)</source><creator>Tatar, D. ; Özen, G. ; Erim, F. B. ; Öveçoǧlu, M. L.</creator><creatorcontrib>Tatar, D. ; Özen, G. ; Erim, F. B. ; Öveçoǧlu, M. L.</creatorcontrib><description>The Raman spectroscopy technique was used to characterize the microstructure and the crystallization properties of the as‐cast and heat‐treated binary TeO 2 WO 3 , TeO 2 CdF 2 and ternary TeO 2 CdF 2 WO 3 glasses and glass ceramics. The results were compared with those obtained by using the X‐ray diffraction technique. The effect of the WO 3 and CdF 2 contents on the TeO 2 glass network and the intensity ratios of the deconvoluted Raman peaks were determined. The shifts in the Raman band wavenumbers and the intensity values for each band were investigated. The Raman results indicated that the glasses were mainly formed by the [TeO 4 ] and [TeO 3 ] units. The [TeO 4 ] units convert to [TeO 3 ] units with the addition of WO 3 and CdF 2 into tellurite glasses. All the crystalline phases such as α‐TeO 2 , δ‐TeO 2 and γ‐TeO 2 existing in the TeO 2 WO 3 , TeO 2 CdF 2 and TeO 2 ‐ WO 3 CdF 2 glasses were determined. The transformation of the metastable γ‐TeO 2 phase into stable α‐TeO 2 was observed for the (1 − x )TeO 2  x WO 3 (where x = 0.15, 0.20, 0.25), 0.90Te 2 0.10CdF 2 , the 0.85TeO 2 0.10CdF 2 0.05WO 3 and 0.80TeO 2 0.10CdF 2 0.10WO 3 glasses, and the transformation of the metastable δ‐TeO 2 phase into the stable α‐TeO 2 was also observed for the TeO 2 CdF 2 WO 3 glass system. In addition, an unidentified phase formation, labeled ε, was determined. Copyright © 2009 John Wiley &amp; Sons, Ltd.</description><identifier>ISSN: 0377-0486</identifier><identifier>EISSN: 1097-4555</identifier><identifier>DOI: 10.1002/jrs.2519</identifier><language>eng</language><ispartof>Journal of Raman spectroscopy, 2010-07, Vol.41 (7), p.797-807</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c729-e348df59c8f1cbe9d717158a668dcca4e74ead602b203fc6341faa8ed5f95daf3</citedby><cites>FETCH-LOGICAL-c729-e348df59c8f1cbe9d717158a668dcca4e74ead602b203fc6341faa8ed5f95daf3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Tatar, D.</creatorcontrib><creatorcontrib>Özen, G.</creatorcontrib><creatorcontrib>Erim, F. B.</creatorcontrib><creatorcontrib>Öveçoǧlu, M. L.</creatorcontrib><title>Raman characterizations and structural properties of the binary TeO 2 WO 3 , TeO 2 CdF 2 and ternary TeO 2 CdF 2 WO 3 glasses</title><title>Journal of Raman spectroscopy</title><description>The Raman spectroscopy technique was used to characterize the microstructure and the crystallization properties of the as‐cast and heat‐treated binary TeO 2 WO 3 , TeO 2 CdF 2 and ternary TeO 2 CdF 2 WO 3 glasses and glass ceramics. The results were compared with those obtained by using the X‐ray diffraction technique. The effect of the WO 3 and CdF 2 contents on the TeO 2 glass network and the intensity ratios of the deconvoluted Raman peaks were determined. The shifts in the Raman band wavenumbers and the intensity values for each band were investigated. The Raman results indicated that the glasses were mainly formed by the [TeO 4 ] and [TeO 3 ] units. The [TeO 4 ] units convert to [TeO 3 ] units with the addition of WO 3 and CdF 2 into tellurite glasses. All the crystalline phases such as α‐TeO 2 , δ‐TeO 2 and γ‐TeO 2 existing in the TeO 2 WO 3 , TeO 2 CdF 2 and TeO 2 ‐ WO 3 CdF 2 glasses were determined. The transformation of the metastable γ‐TeO 2 phase into stable α‐TeO 2 was observed for the (1 − x )TeO 2  x WO 3 (where x = 0.15, 0.20, 0.25), 0.90Te 2 0.10CdF 2 , the 0.85TeO 2 0.10CdF 2 0.05WO 3 and 0.80TeO 2 0.10CdF 2 0.10WO 3 glasses, and the transformation of the metastable δ‐TeO 2 phase into the stable α‐TeO 2 was also observed for the TeO 2 CdF 2 WO 3 glass system. In addition, an unidentified phase formation, labeled ε, was determined. Copyright © 2009 John Wiley &amp; Sons, Ltd.</description><issn>0377-0486</issn><issn>1097-4555</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNpVkMFKxDAQhoMoWFfBR8jRg12TpkmaoxRXhYUFWfBYpsnE7bLblqR70DfwOXwQH8lXsMsq4mlm-Gc-ho-QS86mnLHsZh3iNJPcHJGEM6PTXEp5TBImtE5ZXqhTchbjmjFmjOIJeX-CLbTUriCAHTA0bzA0XRsptI7GIezssAuwoX3oegxDg5F2ng4rpHXTQnilS1zQjH59fD4vqKDXf3PpZmOzx4zY_6uH6PfmZQMxYjwnJx42ES9-6oQsZ3fL8iGdL-4fy9t5anVmUhR54bw0tvDc1mic5prLApQqnLWQo84RnGJZnTHhrRI59wAFOumNdODFhFwdsDZ0MQb0VR-a7fhexVm1N1iNBqu9QfENqfJnxQ</recordid><startdate>201007</startdate><enddate>201007</enddate><creator>Tatar, D.</creator><creator>Özen, G.</creator><creator>Erim, F. B.</creator><creator>Öveçoǧlu, M. L.</creator><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>201007</creationdate><title>Raman characterizations and structural properties of the binary TeO 2 WO 3 , TeO 2 CdF 2 and ternary TeO 2 CdF 2 WO 3 glasses</title><author>Tatar, D. ; Özen, G. ; Erim, F. B. ; Öveçoǧlu, M. L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c729-e348df59c8f1cbe9d717158a668dcca4e74ead602b203fc6341faa8ed5f95daf3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tatar, D.</creatorcontrib><creatorcontrib>Özen, G.</creatorcontrib><creatorcontrib>Erim, F. B.</creatorcontrib><creatorcontrib>Öveçoǧlu, M. L.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of Raman spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tatar, D.</au><au>Özen, G.</au><au>Erim, F. B.</au><au>Öveçoǧlu, M. L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Raman characterizations and structural properties of the binary TeO 2 WO 3 , TeO 2 CdF 2 and ternary TeO 2 CdF 2 WO 3 glasses</atitle><jtitle>Journal of Raman spectroscopy</jtitle><date>2010-07</date><risdate>2010</risdate><volume>41</volume><issue>7</issue><spage>797</spage><epage>807</epage><pages>797-807</pages><issn>0377-0486</issn><eissn>1097-4555</eissn><abstract>The Raman spectroscopy technique was used to characterize the microstructure and the crystallization properties of the as‐cast and heat‐treated binary TeO 2 WO 3 , TeO 2 CdF 2 and ternary TeO 2 CdF 2 WO 3 glasses and glass ceramics. The results were compared with those obtained by using the X‐ray diffraction technique. The effect of the WO 3 and CdF 2 contents on the TeO 2 glass network and the intensity ratios of the deconvoluted Raman peaks were determined. The shifts in the Raman band wavenumbers and the intensity values for each band were investigated. The Raman results indicated that the glasses were mainly formed by the [TeO 4 ] and [TeO 3 ] units. The [TeO 4 ] units convert to [TeO 3 ] units with the addition of WO 3 and CdF 2 into tellurite glasses. All the crystalline phases such as α‐TeO 2 , δ‐TeO 2 and γ‐TeO 2 existing in the TeO 2 WO 3 , TeO 2 CdF 2 and TeO 2 ‐ WO 3 CdF 2 glasses were determined. The transformation of the metastable γ‐TeO 2 phase into stable α‐TeO 2 was observed for the (1 − x )TeO 2  x WO 3 (where x = 0.15, 0.20, 0.25), 0.90Te 2 0.10CdF 2 , the 0.85TeO 2 0.10CdF 2 0.05WO 3 and 0.80TeO 2 0.10CdF 2 0.10WO 3 glasses, and the transformation of the metastable δ‐TeO 2 phase into the stable α‐TeO 2 was also observed for the TeO 2 CdF 2 WO 3 glass system. In addition, an unidentified phase formation, labeled ε, was determined. Copyright © 2009 John Wiley &amp; Sons, Ltd.</abstract><doi>10.1002/jrs.2519</doi><tpages>11</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0377-0486
ispartof Journal of Raman spectroscopy, 2010-07, Vol.41 (7), p.797-807
issn 0377-0486
1097-4555
language eng
recordid cdi_crossref_primary_10_1002_jrs_2519
source Wiley:Jisc Collections:Wiley Read and Publish Open Access 2024-2025 (reading list)
title Raman characterizations and structural properties of the binary TeO 2 WO 3 , TeO 2 CdF 2 and ternary TeO 2 CdF 2 WO 3 glasses
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-23T17%3A37%3A09IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-crossref&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Raman%20characterizations%20and%20structural%20properties%20of%20the%20binary%20TeO%202%20%EF%A3%BFWO%203%20,%20TeO%202%20%EF%A3%BFCdF%202%20and%20ternary%20TeO%202%20%EF%A3%BFCdF%202%20%EF%A3%BFWO%203%20glasses&rft.jtitle=Journal%20of%20Raman%20spectroscopy&rft.au=Tatar,%20D.&rft.date=2010-07&rft.volume=41&rft.issue=7&rft.spage=797&rft.epage=807&rft.pages=797-807&rft.issn=0377-0486&rft.eissn=1097-4555&rft_id=info:doi/10.1002/jrs.2519&rft_dat=%3Ccrossref%3E10_1002_jrs_2519%3C/crossref%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c729-e348df59c8f1cbe9d717158a668dcca4e74ead602b203fc6341faa8ed5f95daf3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true