Alternating Diene Metathesis Polycondensation (ALTMET) - A Versatile Tool for the Preparation of Perfectly Alternating AB Copolymers

Perfectly alternating copolymers can be synthesised by reacting diacrylates with terminal dienes using alternating diene metathesis polycondensation (ALTMET). This novel method is very versatile and allows preparation of diverse structures of polymers, including main‐chain liquid crystalline polymer...

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Bibliographic Details
Published in:Macromolecular rapid communications. 2003-07, Vol.24 (10), p.636-641
Main Authors: Demel, Sandra, Slugovc, Christian, Stelzer, Franz, Fodor-Csorba, Katalin, Galli, Giancarlo
Format: Article
Language:English
Subjects:
ADMET
alternating copolymers
Applied sciences
Copolymerization
Exact sciences and technology
insertion metathesis
liquid crystalline polymers
Organic polymers
Physicochemistry of polymers
Preparation, kinetics, thermodynamics, mechanism and catalysts
ruthenium
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Summary:Perfectly alternating copolymers can be synthesised by reacting diacrylates with terminal dienes using alternating diene metathesis polycondensation (ALTMET). This novel method is very versatile and allows preparation of diverse structures of polymers, including main‐chain liquid crystalline polymers. Main‐chain liquid crystalline polymer obtained by ALTMET.
ISSN:1022-1336
1521-3927
DOI:10.1002/marc.200350007