Fabrication of Micropatterned Gold Nanoparticle Arrays as a Template for Surface-Initiated Polymerization of Stimuli-Responsive Polymers

This paper demonstrates a new, reliable, and simple method for fabricating micropatterned nanoparticle arrays that can serve as templates for the surface‐initiated polymerization of polymer brushes. As a proof of concept, we micropatterned gold nanoparticles (Au‐NPs, ≈10 nm) onto glass, silicon, pol...

Full description

Saved in:
Bibliographic Details
Published in:Macromolecular rapid communications. 2006-05, Vol.27 (10), p.776-780
Main Authors: Jung, Jaeyoen, Kim, Ki Woo, Na, Kyunga, Kaholek, Marian, Zauscher, Stefan, Hyun, Jinho
Format: Article
Language:English
Subjects:
Applied sciences
atomic force microscopy (AFM)
Exact sciences and technology
micropatterning
nanoparticles
Organic polymers
Physicochemistry of polymers
poly(N-isopropylacrylamide)
Properties and characterization
Structure, morphology and analysis
templates
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c3579-c4f7854b72e0f3846372d4e3c08d4feb6d7ae7f01bd18bfcfb6732da75879ac53
cites cdi_FETCH-LOGICAL-c3579-c4f7854b72e0f3846372d4e3c08d4feb6d7ae7f01bd18bfcfb6732da75879ac53
container_end_page 780
container_issue 10
container_start_page 776
container_title Macromolecular rapid communications.
container_volume 27
creator Jung, Jaeyoen
Kim, Ki Woo
Na, Kyunga
Kaholek, Marian
Zauscher, Stefan
Hyun, Jinho
description This paper demonstrates a new, reliable, and simple method for fabricating micropatterned nanoparticle arrays that can serve as templates for the surface‐initiated polymerization of polymer brushes. As a proof of concept, we micropatterned gold nanoparticles (Au‐NPs, ≈10 nm) onto glass, silicon, polystyrene, and gold surfaces by a simple three‐step process: (1) microcontact printing of soluble polymer, (2) incubation with a solution of Au‐NPs, and (3) lift‐off of the template in a mixture of ethanol and deionized water. 40 µm wide features were successfully fabricated without any significant defects or nonspecific adsorption on the background. To demonstrate the utility of these Au‐NP templates, we subsequently polymerized N‐isopropylacrylamide by surface‐initiated polymerization, using a surface‐bound initiator. Synthesis of PNIPAAm brushes from micropatterned Au‐NP.
doi_str_mv 10.1002/marc.200600069
format article
fullrecord <record><control><sourceid>wiley_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_marc_200600069</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>MARC200600069</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3579-c4f7854b72e0f3846372d4e3c08d4feb6d7ae7f01bd18bfcfb6732da75879ac53</originalsourceid><addsrcrecordid>eNqFkF9LwzAUxYsoOP-8-pwXHzvTpG3axzHcJmwq22TgS7hNbyDatSXp1PkJ_NhGptM34YYbLud3bnKC4CKi_YhSdrUGq_qM0pT6kx8EvShhUchzJg79nTIWRpynx8GJc09eksWU9YKPERTWKOhMU5NGk5lRtmmh69DWWJJxU5XkFmo_sp1RFZKBtbB1BHyRJa7bCjokurFksbEaFIY3temMH5bkvqm2a7Tmfe--6Mx6U5lwjq5tamde8EfkzoIjDZXD8-9-GjyMrpfDSTi9G98MB9NQ8UTkoYq1yJK4EAyp5lmccsHKGLmiWRlrLNJSAApNo6KMskIrXaSCsxJEkokcVMJPg_7O1__TOYtattb46LYyovIrR_mVo9zn6IHLHdCCU1BpC7Uy7pcSIs-yJPW6fKd7NRVu_3GVs8F8-HdHuGON6_Btz4J9lv75IpGr27GcPbJpMslXcsU_AXXVlyg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Fabrication of Micropatterned Gold Nanoparticle Arrays as a Template for Surface-Initiated Polymerization of Stimuli-Responsive Polymers</title><source>Wiley-Blackwell Read &amp; Publish Collection</source><creator>Jung, Jaeyoen ; Kim, Ki Woo ; Na, Kyunga ; Kaholek, Marian ; Zauscher, Stefan ; Hyun, Jinho</creator><creatorcontrib>Jung, Jaeyoen ; Kim, Ki Woo ; Na, Kyunga ; Kaholek, Marian ; Zauscher, Stefan ; Hyun, Jinho</creatorcontrib><description>This paper demonstrates a new, reliable, and simple method for fabricating micropatterned nanoparticle arrays that can serve as templates for the surface‐initiated polymerization of polymer brushes. As a proof of concept, we micropatterned gold nanoparticles (Au‐NPs, ≈10 nm) onto glass, silicon, polystyrene, and gold surfaces by a simple three‐step process: (1) microcontact printing of soluble polymer, (2) incubation with a solution of Au‐NPs, and (3) lift‐off of the template in a mixture of ethanol and deionized water. 40 µm wide features were successfully fabricated without any significant defects or nonspecific adsorption on the background. To demonstrate the utility of these Au‐NP templates, we subsequently polymerized N‐isopropylacrylamide by surface‐initiated polymerization, using a surface‐bound initiator. Synthesis of PNIPAAm brushes from micropatterned Au‐NP.</description><identifier>ISSN: 1022-1336</identifier><identifier>EISSN: 1521-3927</identifier><identifier>DOI: 10.1002/marc.200600069</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Applied sciences ; atomic force microscopy (AFM) ; Exact sciences and technology ; micropatterning ; nanoparticles ; Organic polymers ; Physicochemistry of polymers ; poly(N-isopropylacrylamide) ; Properties and characterization ; Structure, morphology and analysis ; templates</subject><ispartof>Macromolecular rapid communications., 2006-05, Vol.27 (10), p.776-780</ispartof><rights>Copyright © 2006 WILEY‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><rights>2006 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3579-c4f7854b72e0f3846372d4e3c08d4feb6d7ae7f01bd18bfcfb6732da75879ac53</citedby><cites>FETCH-LOGICAL-c3579-c4f7854b72e0f3846372d4e3c08d4feb6d7ae7f01bd18bfcfb6732da75879ac53</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=17798856$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Jung, Jaeyoen</creatorcontrib><creatorcontrib>Kim, Ki Woo</creatorcontrib><creatorcontrib>Na, Kyunga</creatorcontrib><creatorcontrib>Kaholek, Marian</creatorcontrib><creatorcontrib>Zauscher, Stefan</creatorcontrib><creatorcontrib>Hyun, Jinho</creatorcontrib><title>Fabrication of Micropatterned Gold Nanoparticle Arrays as a Template for Surface-Initiated Polymerization of Stimuli-Responsive Polymers</title><title>Macromolecular rapid communications.</title><addtitle>Macromol. Rapid Commun</addtitle><description>This paper demonstrates a new, reliable, and simple method for fabricating micropatterned nanoparticle arrays that can serve as templates for the surface‐initiated polymerization of polymer brushes. As a proof of concept, we micropatterned gold nanoparticles (Au‐NPs, ≈10 nm) onto glass, silicon, polystyrene, and gold surfaces by a simple three‐step process: (1) microcontact printing of soluble polymer, (2) incubation with a solution of Au‐NPs, and (3) lift‐off of the template in a mixture of ethanol and deionized water. 40 µm wide features were successfully fabricated without any significant defects or nonspecific adsorption on the background. To demonstrate the utility of these Au‐NP templates, we subsequently polymerized N‐isopropylacrylamide by surface‐initiated polymerization, using a surface‐bound initiator. Synthesis of PNIPAAm brushes from micropatterned Au‐NP.</description><subject>Applied sciences</subject><subject>atomic force microscopy (AFM)</subject><subject>Exact sciences and technology</subject><subject>micropatterning</subject><subject>nanoparticles</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>poly(N-isopropylacrylamide)</subject><subject>Properties and characterization</subject><subject>Structure, morphology and analysis</subject><subject>templates</subject><issn>1022-1336</issn><issn>1521-3927</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2006</creationdate><recordtype>article</recordtype><recordid>eNqFkF9LwzAUxYsoOP-8-pwXHzvTpG3axzHcJmwq22TgS7hNbyDatSXp1PkJ_NhGptM34YYbLud3bnKC4CKi_YhSdrUGq_qM0pT6kx8EvShhUchzJg79nTIWRpynx8GJc09eksWU9YKPERTWKOhMU5NGk5lRtmmh69DWWJJxU5XkFmo_sp1RFZKBtbB1BHyRJa7bCjokurFksbEaFIY3temMH5bkvqm2a7Tmfe--6Mx6U5lwjq5tamde8EfkzoIjDZXD8-9-GjyMrpfDSTi9G98MB9NQ8UTkoYq1yJK4EAyp5lmccsHKGLmiWRlrLNJSAApNo6KMskIrXaSCsxJEkokcVMJPg_7O1__TOYtattb46LYyovIrR_mVo9zn6IHLHdCCU1BpC7Uy7pcSIs-yJPW6fKd7NRVu_3GVs8F8-HdHuGON6_Btz4J9lv75IpGr27GcPbJpMslXcsU_AXXVlyg</recordid><startdate>20060519</startdate><enddate>20060519</enddate><creator>Jung, Jaeyoen</creator><creator>Kim, Ki Woo</creator><creator>Na, Kyunga</creator><creator>Kaholek, Marian</creator><creator>Zauscher, Stefan</creator><creator>Hyun, Jinho</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><general>Wiley</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20060519</creationdate><title>Fabrication of Micropatterned Gold Nanoparticle Arrays as a Template for Surface-Initiated Polymerization of Stimuli-Responsive Polymers</title><author>Jung, Jaeyoen ; Kim, Ki Woo ; Na, Kyunga ; Kaholek, Marian ; Zauscher, Stefan ; Hyun, Jinho</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3579-c4f7854b72e0f3846372d4e3c08d4feb6d7ae7f01bd18bfcfb6732da75879ac53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2006</creationdate><topic>Applied sciences</topic><topic>atomic force microscopy (AFM)</topic><topic>Exact sciences and technology</topic><topic>micropatterning</topic><topic>nanoparticles</topic><topic>Organic polymers</topic><topic>Physicochemistry of polymers</topic><topic>poly(N-isopropylacrylamide)</topic><topic>Properties and characterization</topic><topic>Structure, morphology and analysis</topic><topic>templates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Jung, Jaeyoen</creatorcontrib><creatorcontrib>Kim, Ki Woo</creatorcontrib><creatorcontrib>Na, Kyunga</creatorcontrib><creatorcontrib>Kaholek, Marian</creatorcontrib><creatorcontrib>Zauscher, Stefan</creatorcontrib><creatorcontrib>Hyun, Jinho</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Macromolecular rapid communications.</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jung, Jaeyoen</au><au>Kim, Ki Woo</au><au>Na, Kyunga</au><au>Kaholek, Marian</au><au>Zauscher, Stefan</au><au>Hyun, Jinho</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fabrication of Micropatterned Gold Nanoparticle Arrays as a Template for Surface-Initiated Polymerization of Stimuli-Responsive Polymers</atitle><jtitle>Macromolecular rapid communications.</jtitle><addtitle>Macromol. Rapid Commun</addtitle><date>2006-05-19</date><risdate>2006</risdate><volume>27</volume><issue>10</issue><spage>776</spage><epage>780</epage><pages>776-780</pages><issn>1022-1336</issn><eissn>1521-3927</eissn><abstract>This paper demonstrates a new, reliable, and simple method for fabricating micropatterned nanoparticle arrays that can serve as templates for the surface‐initiated polymerization of polymer brushes. As a proof of concept, we micropatterned gold nanoparticles (Au‐NPs, ≈10 nm) onto glass, silicon, polystyrene, and gold surfaces by a simple three‐step process: (1) microcontact printing of soluble polymer, (2) incubation with a solution of Au‐NPs, and (3) lift‐off of the template in a mixture of ethanol and deionized water. 40 µm wide features were successfully fabricated without any significant defects or nonspecific adsorption on the background. To demonstrate the utility of these Au‐NP templates, we subsequently polymerized N‐isopropylacrylamide by surface‐initiated polymerization, using a surface‐bound initiator. Synthesis of PNIPAAm brushes from micropatterned Au‐NP.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><doi>10.1002/marc.200600069</doi><tpages>5</tpages></addata></record>
fulltext fulltext
identifier ISSN: 1022-1336
ispartof Macromolecular rapid communications., 2006-05, Vol.27 (10), p.776-780
issn 1022-1336
1521-3927
language eng
recordid cdi_crossref_primary_10_1002_marc_200600069
source Wiley-Blackwell Read & Publish Collection
subjects Applied sciences
atomic force microscopy (AFM)
Exact sciences and technology
micropatterning
nanoparticles
Organic polymers
Physicochemistry of polymers
poly(N-isopropylacrylamide)
Properties and characterization
Structure, morphology and analysis
templates
title Fabrication of Micropatterned Gold Nanoparticle Arrays as a Template for Surface-Initiated Polymerization of Stimuli-Responsive Polymers
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-28T21%3A13%3A02IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-wiley_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Fabrication%20of%20Micropatterned%20Gold%20Nanoparticle%20Arrays%20as%20a%20Template%20for%20Surface-Initiated%20Polymerization%20of%20Stimuli-Responsive%20Polymers&rft.jtitle=Macromolecular%20rapid%20communications.&rft.au=Jung,%20Jaeyoen&rft.date=2006-05-19&rft.volume=27&rft.issue=10&rft.spage=776&rft.epage=780&rft.pages=776-780&rft.issn=1022-1336&rft.eissn=1521-3927&rft_id=info:doi/10.1002/marc.200600069&rft_dat=%3Cwiley_cross%3EMARC200600069%3C/wiley_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c3579-c4f7854b72e0f3846372d4e3c08d4feb6d7ae7f01bd18bfcfb6732da75879ac53%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true