Self-Assembly and Dispersion of Chromogenic Molecules: A Versatile and General Approach for Self-Assessing Polymers

• Published in: Macromolecular rapid communications. 2006-12, Vol.27 (23), p.1981-1987
• Main Authors: Kunzelman, Jill, Crenshaw, Brent R., Kinami, Maki, Weder, Christoph
• Format: Article
• Language: English
• Subjects: Applied sciences; cyano-OPVs; Electrical, magnetic and optical properties; Exact sciences and technology; mechanochromic; Organic polymers; Physicochemistry of polymers; Properties and characterization; self-assembly; stimuli-sensitive polymers; thermochromic
• ISSN: 1022-1336; 1521-3927
• DOI: 10.1002/marc.200600642

Self‐assessing polymer blends based on poly(ethylene terephthalate glycol) or linear low‐density polyethylene and small amounts (0.5–2% w/w) of chromogenic sensor dyes are prepared and investigated. The cyano‐substituted oligo(p‐phenylene vinylene) dyes employed in the study exhibit pronounced optical absorption changes upon self‐assembly, because of charge‐transfer interactions or conformation changes. The extent of dye aggregation (and therewith the optical absorption characteristics) in these blends is significantly influenced by exposure to external stimuli. Subjecting appropriately processed samples to either temperatures above their glass transition or mechanical deformation can significantly change the extent of aggregation, which in turn leads to a color change. Mechano‐optical response of a 1.0% w/w LLDPE/C18‐RG blend film. Pristine films are orange due to aggregated dye molecules. Deformation leads to dispersion of the dye and irreversibly changes the color to yellow.