Reduction in smoke emitted and fire hazard presented by flexible poly (vinyl chloride) through novel synthesis of SnO 2 supported by activated carbon spheres

• Published in: Polymers for advanced technologies 2018-09, Vol.29 (9), p.2505-2514
• Main Authors: He, Shaorui, Wu, Weihong, Zhang, Mengjiao, Han, Hongda, Jiao, Yunhong, Qu, Hongqiang, Xu, Jianzhong
• Format: Article
• Language: English
• ISSN: 1042-7147; 1099-1581
• DOI: 10.1002/pat.4362

A novel catalyst consisting of SnO 2 supported by activated carbon spheres (ACS), referred to as “ACS@SnO 2 ,” was demonstrated as being much more efficient than either ACS or SnO 2 alone. As such, it is capable of improving the thermal stability and flame retardancy of flexible poly (vinyl chloride) (fPVC). The resulting ACS@SnO 2 composite exhibits a higher reactivity and excellent stability due to the presence of evenly dispersed SnO 2 particles attached to the ACS, as well as the high degree of graphitization of the ACS. Smoke suppression and the synergistic flame‐retardant effect of the ACS@SnO 2 on the fPVC were thoroughly investigated by performing a cone calorimeter test and thermogravimetric analysis. The cone calorimeter test data reveal that the addition of the ACS@SnO 2 greatly improved the flame retardancy of the fPVC, with 32% and 58.4% decreases in the peak heat release rate and smoke production rate, respectively. This is attributed to the formation of a continuous and compact protective layer and the synergistic effects of the ACS and SnO 2 in promoting the ability of the fPVC to isolate heat and oxygen. Furthermore, the ACS@SnO 2 /fPVC composite produced greatly increased amounts of char residue, thereby attenuating the fire hazard presented by fPVC composites.