Control of transesterification in polyester blends

• Published in: Polymer engineering and science 1989-09, Vol.29 (18), p.1226-1231
• Main Authors: Golovoy, A., Cheung, M.-F., Carduner, K. R., Rokosz, M. J.
• Format: Article
• Language: English
• Subjects: Applied sciences; Compounding ingredients; Exact sciences and technology; Polymer industry, paints, wood; Stabilizers (antioxydants, antiozonants, etc.); Technology of polymers
• ISSN: 0032-3888; 1548-2634
• DOI: 10.1002/pen.760291803

Polyester blends may undergo transesterification during processing, resulting in molecular rearrangements, transient properties, and eventually, degradation. To suppress transesterifcation, the use of organophosphites has been suggested in the patent and technical literature. The effectiveness of organophosphites, however, is variable and sometimes inconsistent. Our recent studies suggest a clue to the inconsistent behavior and provide a simple way to enhance the effectiveness of these stabilizers. Using solid state 31P NMR it was shown that for bis(2,4‐di‐t‐butylphenyl)pentaerythritol diphosphite a conversion of the phosphite group to a phosphonate, via hydrolysis, is a prerequisite for an effective inhibition of transesterification. This conversion occurs readily during melt compounding if the polymers are not completely dry. However, if rigorous drying is employed and phosphite conversion does not occur, then transesterification is not arrested. It was also found that over a period of time the conversion of the phosphite to a phosphonate may take place at room temperature as well. After aging for about a year in the laboratory, the originally ineffective compound, has become a very effective inhibitor of transesterification in blends containing poly(ethylene terephthalate), poly(butylene terephthalate), polycarbonate, and polyarylate. Thus, a simple way to enhance the phosphate effectiveness is to expose it to a humid environment prior to blending.