Fluorine-containing polymers. VII. 1,1-dihydroperfluoroalkyl acrylates: Compounding and properties of vulcanizates

The homopolymer and butadiene copolymers of 1,1‐dihydroperfluorobutyl acrylate form a new class of vulcanizable elastomers with interesting and useful properties, of which solvent resistance is the most outstanding. The homopolymer (poly‐FBA), vulcanized by means of a polyfunctional amine in the pre...

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Bibliographic Details
Published in:Journal of polymer science 1955-02, Vol.15 (80), p.558-574
Main Authors: Stedry, P. J., Abere, J. F., Borders, A. M.
Format: Article
Language:English
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Summary:The homopolymer and butadiene copolymers of 1,1‐dihydroperfluorobutyl acrylate form a new class of vulcanizable elastomers with interesting and useful properties, of which solvent resistance is the most outstanding. The homopolymer (poly‐FBA), vulcanized by means of a polyfunctional amine in the presence of a reinforcing pigment, appears most promising because it offers the following unusual combination of desirable properties: (1) resistance to hydrocarbon solvents; (2) resistance to a variety of lubricants, hydraulic fluids, and similar high boiling liquids at temperatures up to 400°F.; (3) resistance to oxidation by ozone and fuming nitric acid; (4) fair stability and physical properties in air at elevated temperatures. It was shown that many of these properties depend upon compounding recipes and that further improvements can be anticipated.
ISSN:0022-3832
1542-6238
DOI:10.1002/pol.1955.120158023