Radiolysis of the isomeric poly(butyl methacrylates)

A study has been made of the effect of gamma irradiation on the production of free radicals in poly(butyl methacrylates). A mechanism of radiation attack on the polymers is proposed. Free‐radical measurements and the determination of the products of irradiation have been used in establishing this me...

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Bibliographic Details
Published in:Journal of polymer science. Part A. General papers 1963-01, Vol.1 (1), p.277-288
Main Authors: Ungar, Israel S., Kircher, John F., Gager, William B., Sliemers, Francis A., Leininger, Robert I.
Format: Article
Language:English
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Summary:A study has been made of the effect of gamma irradiation on the production of free radicals in poly(butyl methacrylates). A mechanism of radiation attack on the polymers is proposed. Free‐radical measurements and the determination of the products of irradiation have been used in establishing this mechanism. The effects of configuration of the ester chain on radiation susceptibility are discussed.
ISSN:0449-2951
1542-6246
DOI:10.1002/pol.1963.100010125