Polymerization of acrylonitrile catalyzed by methoxo‐β‐diketone nickel chelates

The polymerization of acrylonitrile initiated by methoxo‐β‐diketone nickel chelates of the [Ni(L)(CH 3 O)(CH 3 OH)] n type and pyridine was studied. Chelating agents L employed included acetylacetone, ethylacetoacetate, and salicylaldehyde. These systems could initiate the polymerization of acryloni...

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Published in:Journal of polymer science. Part A-1, Polymer chemistry Polymer chemistry, 1970-08, Vol.8 (8), p.1981-1986
Main Authors: Shono, T., Mori, M., Shinra, K.
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Language:English
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cited_by cdi_FETCH-LOGICAL-c177t-a17dfb04a6331706699035116b7d066cfef60bc9164b098d50699cbc117166343
cites cdi_FETCH-LOGICAL-c177t-a17dfb04a6331706699035116b7d066cfef60bc9164b098d50699cbc117166343
container_end_page 1986
container_issue 8
container_start_page 1981
container_title Journal of polymer science. Part A-1, Polymer chemistry
container_volume 8
creator Shono, T.
Mori, M.
Shinra, K.
description The polymerization of acrylonitrile initiated by methoxo‐β‐diketone nickel chelates of the [Ni(L)(CH 3 O)(CH 3 OH)] n type and pyridine was studied. Chelating agents L employed included acetylacetone, ethylacetoacetate, and salicylaldehyde. These systems could initiate the polymerization of acrylonitrile at −40°C. The polymerization is thought to occur by an anionic coordination mechanism.
doi_str_mv 10.1002/pol.1970.150080807
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title Polymerization of acrylonitrile catalyzed by methoxo‐β‐diketone nickel chelates
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