Synthesis of titanium polythioethers

The synthesis of polythioethers of the form magnified image was effected, where C p denotes cyclopentadienyl. Four reaction systems were studied and evaluated. Two proved to be undesirable (the “reverse” interfacial and organic solution methods), while two proved acceptable (the “normal” interfacial...

Full description

Saved in:
Bibliographic Details
Published in:Journal of polymer science. Part A-1, Polymer chemistry Polymer chemistry, 1972-02, Vol.10 (2), p.521-531
Main Authors: Carraher Jr, Charles E., Nordin, Robert J.
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The synthesis of polythioethers of the form magnified image was effected, where C p denotes cyclopentadienyl. Four reaction systems were studied and evaluated. Two proved to be undesirable (the “reverse” interfacial and organic solution methods), while two proved acceptable (the “normal” interfacial and aqueous solution methods). A number of added bases were evaluated. Et 3 N and NaOH were found to be acceptable. Yield increases with reaction time for aqueous solution syntheses, while yield remains constant with reaction time for synthesis via the normal interfacial method.
ISSN:0449-296X
1542-9350
DOI:10.1002/pol.1972.150100217