Loading…
The effect of anhydrous ammonia on the crystalline-state deformation of nylons 6 and 6,6
The aliphatic polyamides nylon 6 and 6,6 have been cold drawn by using the new concept of reversible plasticization with NH 3 . Two aspects were investigated: the effect of NH 3 plasticization on the stress‐strain behavior of nylon 6,6, and the extent of NH 3 absorption as determined by x‐ray analys...
Saved in:
| Published in: | Journal of polymer science. Polymer physics edition 1982-08, Vol.20 (8), p.1485-1496 |
|---|---|
| Main Authors: | , , |
| Format: | Article |
| Language: | English |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c264t-a4d58ac7e848bd05fe3e89047f9cb3b6204b184a64443f8807dff9a4ff5699383 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c264t-a4d58ac7e848bd05fe3e89047f9cb3b6204b184a64443f8807dff9a4ff5699383 |
| container_end_page | 1496 |
| container_issue | 8 |
| container_start_page | 1485 |
| container_title | Journal of polymer science. Polymer physics edition |
| container_volume | 20 |
| creator | Kanamoto, Tetsuo Zachariades, Anagnostis E. Porter, Roger S. |
| description | The aliphatic polyamides nylon 6 and 6,6 have been cold drawn by using the new concept of reversible plasticization with NH
3
. Two aspects were investigated: the effect of NH
3
plasticization on the stress‐strain behavior of nylon 6,6, and the extent of NH
3
absorption as determined by x‐ray analysis for the structurally simpler nylon 6. X‐ray analysis shows that ammonia is absorbed preferentially by the amorphous phase and that the plasticization has a significant effect on the unit‐cell orientation, the small‐angle void scattering, and the interplanar spacings between sheets of hydrogen‐bonded chains. The effect of plasticization was seen in the lower yield stress, the higher draw ratio (up to 8X) and tensile modulus (10 GPa) not attainable with unplasticized specimens. |
| doi_str_mv | 10.1002/pol.1982.180200813 |
| format | article |
| fullrecord | <record><control><sourceid>istex_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_pol_1982_180200813</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ark_67375_WNG_9GR09Z87_H</sourcerecordid><originalsourceid>FETCH-LOGICAL-c264t-a4d58ac7e848bd05fe3e89047f9cb3b6204b184a64443f8807dff9a4ff5699383</originalsourceid><addsrcrecordid>eNo9kM1KAzEUhYMoWKsv4CoP4NSbn8nPUoq2gihIRXETMjMJHZ2ZlGQE5-1NqXR1z-J8B-6H0DWBBQGgt7vQLYhWdEEUUABF2AmakZLTQjNVnqIZgFYFoZKdo4uUvgAYASlm6GOzddh57-oRB4_tsJ2aGH4Stn0fhtbiMOAxV-o4pdF2XTu4IofR4cb5EHs7trmRyWHqwpCwyBMNFjfiEp152yV39X_n6O3hfrNcF08vq8fl3VNRU8HHwvKmVLaWTnFVNVB6x5zSwKXXdcUqQYFXRHErOOfMKwWy8V5b7n0pdP6NzRE97NYxpBSdN7vY9jZOhoDZuzHZjdm7MUc3GSoOUJtG93skbPw2QjJZmvfnldGrV9CfSpo1-wMzWmbt</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>The effect of anhydrous ammonia on the crystalline-state deformation of nylons 6 and 6,6</title><source>Wiley Online Library Polymer Backfiles</source><creator>Kanamoto, Tetsuo ; Zachariades, Anagnostis E. ; Porter, Roger S.</creator><creatorcontrib>Kanamoto, Tetsuo ; Zachariades, Anagnostis E. ; Porter, Roger S.</creatorcontrib><description>The aliphatic polyamides nylon 6 and 6,6 have been cold drawn by using the new concept of reversible plasticization with NH
3
. Two aspects were investigated: the effect of NH
3
plasticization on the stress‐strain behavior of nylon 6,6, and the extent of NH
3
absorption as determined by x‐ray analysis for the structurally simpler nylon 6. X‐ray analysis shows that ammonia is absorbed preferentially by the amorphous phase and that the plasticization has a significant effect on the unit‐cell orientation, the small‐angle void scattering, and the interplanar spacings between sheets of hydrogen‐bonded chains. The effect of plasticization was seen in the lower yield stress, the higher draw ratio (up to 8X) and tensile modulus (10 GPa) not attainable with unplasticized specimens.</description><identifier>ISSN: 0098-1273</identifier><identifier>EISSN: 1542-9385</identifier><identifier>DOI: 10.1002/pol.1982.180200813</identifier><language>eng</language><publisher>New York: John Wiley & Sons, Inc</publisher><ispartof>Journal of polymer science. Polymer physics edition, 1982-08, Vol.20 (8), p.1485-1496</ispartof><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c264t-a4d58ac7e848bd05fe3e89047f9cb3b6204b184a64443f8807dff9a4ff5699383</citedby><cites>FETCH-LOGICAL-c264t-a4d58ac7e848bd05fe3e89047f9cb3b6204b184a64443f8807dff9a4ff5699383</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Kanamoto, Tetsuo</creatorcontrib><creatorcontrib>Zachariades, Anagnostis E.</creatorcontrib><creatorcontrib>Porter, Roger S.</creatorcontrib><title>The effect of anhydrous ammonia on the crystalline-state deformation of nylons 6 and 6,6</title><title>Journal of polymer science. Polymer physics edition</title><addtitle>J. Polym. Sci. Polym. Phys. Ed</addtitle><description>The aliphatic polyamides nylon 6 and 6,6 have been cold drawn by using the new concept of reversible plasticization with NH
3
. Two aspects were investigated: the effect of NH
3
plasticization on the stress‐strain behavior of nylon 6,6, and the extent of NH
3
absorption as determined by x‐ray analysis for the structurally simpler nylon 6. X‐ray analysis shows that ammonia is absorbed preferentially by the amorphous phase and that the plasticization has a significant effect on the unit‐cell orientation, the small‐angle void scattering, and the interplanar spacings between sheets of hydrogen‐bonded chains. The effect of plasticization was seen in the lower yield stress, the higher draw ratio (up to 8X) and tensile modulus (10 GPa) not attainable with unplasticized specimens.</description><issn>0098-1273</issn><issn>1542-9385</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1982</creationdate><recordtype>article</recordtype><recordid>eNo9kM1KAzEUhYMoWKsv4CoP4NSbn8nPUoq2gihIRXETMjMJHZ2ZlGQE5-1NqXR1z-J8B-6H0DWBBQGgt7vQLYhWdEEUUABF2AmakZLTQjNVnqIZgFYFoZKdo4uUvgAYASlm6GOzddh57-oRB4_tsJ2aGH4Stn0fhtbiMOAxV-o4pdF2XTu4IofR4cb5EHs7trmRyWHqwpCwyBMNFjfiEp152yV39X_n6O3hfrNcF08vq8fl3VNRU8HHwvKmVLaWTnFVNVB6x5zSwKXXdcUqQYFXRHErOOfMKwWy8V5b7n0pdP6NzRE97NYxpBSdN7vY9jZOhoDZuzHZjdm7MUc3GSoOUJtG93skbPw2QjJZmvfnldGrV9CfSpo1-wMzWmbt</recordid><startdate>198208</startdate><enddate>198208</enddate><creator>Kanamoto, Tetsuo</creator><creator>Zachariades, Anagnostis E.</creator><creator>Porter, Roger S.</creator><general>John Wiley & Sons, Inc</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>198208</creationdate><title>The effect of anhydrous ammonia on the crystalline-state deformation of nylons 6 and 6,6</title><author>Kanamoto, Tetsuo ; Zachariades, Anagnostis E. ; Porter, Roger S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c264t-a4d58ac7e848bd05fe3e89047f9cb3b6204b184a64443f8807dff9a4ff5699383</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1982</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Kanamoto, Tetsuo</creatorcontrib><creatorcontrib>Zachariades, Anagnostis E.</creatorcontrib><creatorcontrib>Porter, Roger S.</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Journal of polymer science. Polymer physics edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kanamoto, Tetsuo</au><au>Zachariades, Anagnostis E.</au><au>Porter, Roger S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>The effect of anhydrous ammonia on the crystalline-state deformation of nylons 6 and 6,6</atitle><jtitle>Journal of polymer science. Polymer physics edition</jtitle><addtitle>J. Polym. Sci. Polym. Phys. Ed</addtitle><date>1982-08</date><risdate>1982</risdate><volume>20</volume><issue>8</issue><spage>1485</spage><epage>1496</epage><pages>1485-1496</pages><issn>0098-1273</issn><eissn>1542-9385</eissn><abstract>The aliphatic polyamides nylon 6 and 6,6 have been cold drawn by using the new concept of reversible plasticization with NH
3
. Two aspects were investigated: the effect of NH
3
plasticization on the stress‐strain behavior of nylon 6,6, and the extent of NH
3
absorption as determined by x‐ray analysis for the structurally simpler nylon 6. X‐ray analysis shows that ammonia is absorbed preferentially by the amorphous phase and that the plasticization has a significant effect on the unit‐cell orientation, the small‐angle void scattering, and the interplanar spacings between sheets of hydrogen‐bonded chains. The effect of plasticization was seen in the lower yield stress, the higher draw ratio (up to 8X) and tensile modulus (10 GPa) not attainable with unplasticized specimens.</abstract><cop>New York</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/pol.1982.180200813</doi><tpages>12</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0098-1273 |
| ispartof | Journal of polymer science. Polymer physics edition, 1982-08, Vol.20 (8), p.1485-1496 |
| issn | 0098-1273 1542-9385 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_pol_1982_180200813 |
| source | Wiley Online Library Polymer Backfiles |
| title | The effect of anhydrous ammonia on the crystalline-state deformation of nylons 6 and 6,6 |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-19T15%3A04%3A10IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-istex_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=The%20effect%20of%20anhydrous%20ammonia%20on%20the%20crystalline-state%20deformation%20of%20nylons%206%20and%206,6&rft.jtitle=Journal%20of%20polymer%20science.%20Polymer%20physics%20edition&rft.au=Kanamoto,%20Tetsuo&rft.date=1982-08&rft.volume=20&rft.issue=8&rft.spage=1485&rft.epage=1496&rft.pages=1485-1496&rft.issn=0098-1273&rft.eissn=1542-9385&rft_id=info:doi/10.1002/pol.1982.180200813&rft_dat=%3Cistex_cross%3Eark_67375_WNG_9GR09Z87_H%3C/istex_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c264t-a4d58ac7e848bd05fe3e89047f9cb3b6204b184a64443f8807dff9a4ff5699383%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |