Polymerization using palladium (II) salts. III. Polymerization of 4-bromo-4′-ethynyl biphenyl

The monomer 4‐bromo‐4′‐ethynyl biphenyl was synthesized and subsequently polymerized utilizing a bis (triphenylphosphine) palladium (II) chloride, copper (I) iodide, triphenylphosphine catalyst system in an organic amine solvent(s). The polymers produced were predominantly insoluble materials with r...

Full description

Saved in:
Bibliographic Details
Published in:Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 1987-03, Vol.25 (3), p.839-846
Main Authors: Trumbo, D. L., Marvel, C. S.
Format: Article
Language:English
Subjects:
Applied sciences
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymerization
Preparation, kinetics, thermodynamics, mechanism and catalysts
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The monomer 4‐bromo‐4′‐ethynyl biphenyl was synthesized and subsequently polymerized utilizing a bis (triphenylphosphine) palladium (II) chloride, copper (I) iodide, triphenylphosphine catalyst system in an organic amine solvent(s). The polymers produced were predominantly insoluble materials with reasonable thermal stability.
ISSN:0887-624X
1099-0518
DOI:10.1002/pola.1987.080250309