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Thermally reversible, covalently crosslinked polyphosphazenes

The concept of thermally reversible crosslinking was investigated by using poly[bis(trifluoroethoxy)phosphazenes] with different percentages of cyclopentadienylethoxy and dicyclopentadienyldiethoxy substituent groups. The resultant structures of these polymers are discussed and the phenomenon of rev...

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Bibliographic Details
Published in:Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 1988-10, Vol.26 (11), p.2923-2939
Main Authors: Salamone, J. C., Chung, Y., Clough, S. B., Watterson, A. C.
Format: Article
Language:English
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Summary:The concept of thermally reversible crosslinking was investigated by using poly[bis(trifluoroethoxy)phosphazenes] with different percentages of cyclopentadienylethoxy and dicyclopentadienyldiethoxy substituent groups. The resultant structures of these polymers are discussed and the phenomenon of reversible crosslinking is demonstrated by means of a DSC study and solubility behavior.
ISSN:0887-624X
1099-0518
DOI:10.1002/pola.1988.080261106