Thioether glycidyl resins. VI. Reaction products of opening of oxirane ring of phenylthioetherglycidyl resin and of some derivatives under the influence of temperature

The process of oxirane ring opening of thioether glycidyl resins under various temperatures has been described. Reaction rate constants (k) and the activaton parameters (Eα, ΔH*, ΔS*) for epoxy group loss of 1,2‐epoxy‐3‐(phenylthio)propane, 1,2‐epoxy‐3‐(p‐tolythio)propane, and 1,2‐epoxy‐3‐(p‐chloro‐...

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Published in:Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 1989-06, Vol.27 (7), p.2397-2415
Main Authors: Charmas, Władysław, Podkościelny, Wawrzyniec, Brunn, Joachim
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Language:English
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description The process of oxirane ring opening of thioether glycidyl resins under various temperatures has been described. Reaction rate constants (k) and the activaton parameters (Eα, ΔH*, ΔS*) for epoxy group loss of 1,2‐epoxy‐3‐(phenylthio)propane, 1,2‐epoxy‐3‐(p‐tolythio)propane, and 1,2‐epoxy‐3‐(p‐chloro‐phenylthio)propane using classical kinetic methods were determined. The reaction products were separated and analyzed by means of chromatography and the structure of the compounds was determined by means of the spectral analyses: IR, 1H‐NMR, and 13C‐NMR
doi_str_mv 10.1002/pola.1989.080270721
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title Thioether glycidyl resins. VI. Reaction products of opening of oxirane ring of phenylthioetherglycidyl resin and of some derivatives under the influence of temperature
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