An environmentally benign room temperature aqueous homo‐ and copolymerization of styrene and methylmethacrylate catalyzed by [Cp 2 TiCl 2 ]/NaBPh 4

[Cp 2 TiCl 2 ] has been found to be an effective precatalyst for room temperature aqueous homo‐ and copolymerization of methyl methacrylate and styrene in the presence of a cocatalyst, NaBPh 4 and an emulsifier, sodium n ‐dodecyl sulfate. The polymers obtained are of high molecular weight with low m...

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Bibliographic Details
Published in:Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2009-12, Vol.47 (23), p.6496-6503
Main Authors: De, Sudip K., Bhattacharjee, Manish
Format: Article
Language:English
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Summary:[Cp 2 TiCl 2 ] has been found to be an effective precatalyst for room temperature aqueous homo‐ and copolymerization of methyl methacrylate and styrene in the presence of a cocatalyst, NaBPh 4 and an emulsifier, sodium n ‐dodecyl sulfate. The polymers obtained are of high molecular weight with low molecular weight distribution. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 6496–6503, 2009
ISSN:0887-624X
1099-0518
DOI:10.1002/pola.23692