Improved Dielectric, Magnetic, and Multiferroic Properties of (Bi 0.5 Na 0.5 ) 0.7 La 0.3 (Ti 0.7 Fe 0.3 )O 3 Ceramics Synthesis by the Solid‐State Combustion Technique

• Published in: Physica status solidi. A, Applications and materials science Applications and materials science, 2024-06
• Main Authors: Kornphom, Chittakorn, Somsri, Widchaya, Prasertpalichat, Sasipohn, Thatawong, Bhoowadol, Kruea‐In, Chatchai, Udeye, Thanya, Rittidech, Aurawan, Menkun, Chanagon, Vittayakorn, Naratip, Pinitsoontorn, Supree, Jantaratana, Pongsakorn, Chanlek, Narong, Bongkarn, Theerachai
• Format: Article
• Language: English
• ISSN: 1862-6300; 1862-6319
• DOI: 10.1002/pssa.202300989

Lead‐free (Bi 0.5 Na 0.5 ) 0.7 La 0.3 (Ti 0.7 Fe 0.3 )O 3 ceramics (abbreviated as BNLTF) are synthesized by the solid‐state combustion technique using glycine as fuel. The effect of the firing temperature (calcined between 700 and 800 °C for 2 h and sintered between at 800 and 900 °C for 2 h) on the phase structure, microstructure, electrical, and magnetic properties is investigated. Pure BNLTF powders are obtained with a calcination temperature of 750 °C for 2 h and the crystal size increases from 47 to 62 nm when the calcination temperature increases from 700 to 800 °C. All sintered BNLTF ceramics show a pure perovskite structure with a rhombohedral phase. The average grain size increases with increasing sintering temperatures. A well‐packed microstructure with the highest density (5.98 g cm −3 ), good dielectric properties at room temperature ( ε r ≈ 589 and tan δ ≈ 0.572), soft ferroelectric behavior, and excellent magnetic properties ( M s ≈ 0.091 emu g −1 , M r ≈ 0.0026 emu g −1 ) is obtained from the ceramic sintered at 875 °C for 2 h. The multiferroic BNLTF ceramic sintered at 875 °C has a maximum magnetoelectric coupling coefficient ( α E ≈ 2.08 mV cm −1 Oe −1 ) when the magnetic field is near 4500 Oe.