Surface and electrochemical analysis for the understanding of TiO 2 nanopores/nanotubes changes in post‐elaboration treatment

• Published in: Surface and interface analysis 2011-07, Vol.43 (7), p.1022-1029
• Main Authors: Manole, Claudiu Constantin, Pirvu, Cristian
• Format: Article
• Language: English
• ISSN: 0142-2421; 1096-9918
• DOI: 10.1002/sia.3685

The electrochemical stability of TiO 2 nanoarchitecture fabricated in fluoride electrolyte presented in this paper is related to 2D and 3D geometries that present a shift from nanopores toward nanotubes. The fabrication conditions involve a 60 V applied voltage for 2 hours of anodizing in order to create the ordered structures, in a mixture of low‐water glycerol electrolyte and fluoride. With the use of different ultrasonication times, a variety of nanotubes/nanopores were observed. The surface interfacial aspects were investigated mainly by surface microscopy and hydrophilic/hydrophobic balance for the grown structures ultrasonicated at various periods of time. The electrochemical behavior of the nanotube‐structured surface was performed by potentiodynamic evaluation and electrochemical impedance spectroscopy in a simulated body fluid solution. As a most important result, all surface analysis and electrochemical data interpretation permitted the proposition of a model for elaboration of different nanostructures from nanopores to nanotubes. These different surface nanoarchitectures were obtained as a result of ultrasonication at various periods of time. Copyright © 2010 John Wiley & Sons, Ltd.