Phosphorus Ester Containing Mesoporous Silica as Novel High‐Effective Flame Retardant in Polyurethane and Polyester Coatings

• Published in: ChemistrySelect (Weinheim) 2021-07, Vol.6 (25), p.6541-6547
• Main Authors: Aytan, Emre, Aytan, Tuğçe Akbal, Kahraman, Memet Vezir
• Format: Article
• Language: English
• Subjects: Green chemistry; Mesoporous Materials; Photochemistry; Polymers
• ISSN: 2365-6549; 2365-6549
• DOI: 10.1002/slct.202100708

In this study mesoporous silica spheres (MPSs) and polyphosphoric acid based organophosphate ester flame retardant (FR material) material were synthesized and flame retardancy performance in acrylate‐based polyurethanes (PUR) and polyester (PET) resins investigated. For this, both MPSs and FR material were synthesized according to literature and FR material was loaded into MPSs which takes the role of carrier. Loaded MPSs were put into UV curable PUR and PET resins and polymerized under UV radiation. Their characteristics were investigated by FT‐IR, TGA, LOI, SEM and TEM. The results showed that FR material had excellent flame‐retardant abilities for both PUR and PET series. The TGA curves suggested that synthesized FR material shows lower thermal stability at low temperatures than original materials however it showed good ability of char formation at higher temperatures, therefore improving the flame retardant property of samples. Moreover the LOI analysis showed that flame retardancy properties were improved significantly. The additive increased the LOI value from 20,5 and 21 to 26,5 and 27. Mesoporous‐silica spheres and polyphosphoric‐acid based organophosphate ester flame retardant (FR) material were synthesized and FR performance in acrylate‐based polyurethanes and polyester resins investigated. TGA curves suggested that FR material shows lower thermal stability at low temperatures than originals however it showed good ability of char formation at higher temperatures, therefore improving the FR property of samples. Moreover the LOI analysis showed that FR properties were improved significantly. Additive increased the LOI value from 20,5 and 21 to 26,5 and 27.