Synthesis, Characterization and Optical Properties of Oxidized Poly Vinyl Alcohol

• Published in: ChemistrySelect (Weinheim) 2022-01, Vol.7 (3), p.n/a
• Main Authors: Charradi, Khaled, Daoudi, Mahmoud, Chemek, Mourad, Ahmed, zakarya, Alzahrani, Abdullah Y. A., Siai, Amira, Chtourou, Radhouane, Keshk, Sherif M. A. S.
• Format: Article
• Language: English
• Subjects: Absorption; alcohol; Charge transfer; Photoluminescence; Poly vinyl; Proton conductivity
• ISSN: 2365-6549; 2365-6549
• DOI: 10.1002/slct.202103273

Poly (viny1 alcohol) (PVA) was partially oxidized by alkaline KMnO4 with an average carbonyl percentage of 65 %. PVA's photo physicochemical properties before and after the oxidation (OPVA) were investigated. The FTIR spectrum of OPVA revealed a new band at 1645 cm−1, corresponding to the carbonyl group and the XRD pattern reflecting an increase in the degree of crystallinity. Unlike pristine PVA, the UV‐vis absorption spectra displayed the most attractive results through OPVA absorption in UV and visible regions. Furthermore, the photoluminescence spectra of PVA membrane exhibited a narrow emission at 338 nm, whereas the OPVA membrane showed blue emission at 415 nm. The proton conductivity increased from 1.5 mScm−1 in PVA to 11.1 mScm−1 in OPVA at 70 °C. Thus, the presence of both hydroxyl and carbonyl groups in OPVA results in the formation of strong hydrogen bonding that facilitate proton transfers along the hydrogen‐bond network. The partial oxidation of PVA (OPVA) enhanced absorption ability with better emission and proton conductivity properties than that of PVA making OPVA an attractive organic polymer in optoelectronics applications, such as sensors, solar cells, capacitors, transistors, diodes etc.’