Structural Consequences of S → Se Substitution in some Symmetrical [M(S2CNR2)3] Complexes

The consequences of replacement of the symmetrically chelate ligands in [M(E2CNR2)3] (E = S, Se) complexes of potential 32 symmetry by analogous mixed S,Se unsymmetrical chelates are explored for both small (M = Co) and large (M = In) metal atoms, and R = primary (Et) and secondary (iPr) alkyl subst...

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Published in:Zeitschrift für anorganische und allgemeine Chemie (1950) 2006-11, Vol.632 (15), p.2419-2423
Main Authors: Dietzsch, Wolfgang, Duffy, Norman V., Lee, Aaron M., Skelton, Brian W., White, Allan H.
Format: Article
Language:English
Subjects:
Cobalt complexes
Coordination chemistry
Crystal structures
Dithiocarbamate complexes
Indium complexes
S ligands
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Summary:The consequences of replacement of the symmetrically chelate ligands in [M(E2CNR2)3] (E = S, Se) complexes of potential 32 symmetry by analogous mixed S,Se unsymmetrical chelates are explored for both small (M = Co) and large (M = In) metal atoms, and R = primary (Et) and secondary (iPr) alkyl substituents by way of low‐temperature single crystal X‐ray studies of [(Co(SSeCNEt2)3] ([Co(Se2CNEt2)3] also determined as datum), and [In(SSeCNR2)3], R = Et, iPr. The structure of [(iPr2N·CS·Se)2] is also recorded.
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.200600207