Synthesis, IR Spectrum, Thermal Analysis, and Crystal Structure of the Cyano-bridged Heteronuclear Polymeric Complex: [Zn(teta)Ni(μ-CN)2(CN)2]n

The heteronuclear polymeric complex, [Zn(teta)Ni(μ‐CN)2(CN)2]n (teta: triethylenetetramine), was synthesized and characterized by elementel analysis, FT‐IR spectroscopy, thermal analysis and single crystal X–ray diffraction techniques. The complex crystallizes in the monoclinic system, space group P...

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Bibliographic Details
Published in:Zeitschrift für anorganische und allgemeine Chemie (1950) 2009-01, Vol.635 (1), p.175-178
Main Authors: Kürkçüoğlu, Güneş Süheyla, Yeşilel, Okan Zafer, Kavlak, Ilkan, Büyükgüngör, Orhan
Format: Article
Language:English
Subjects:
Cyano-bridged complex
Tetracyanonickelate complex
Triethylenetetramine complex
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Summary:The heteronuclear polymeric complex, [Zn(teta)Ni(μ‐CN)2(CN)2]n (teta: triethylenetetramine), was synthesized and characterized by elementel analysis, FT‐IR spectroscopy, thermal analysis and single crystal X–ray diffraction techniques. The complex crystallizes in the monoclinic system, space group P21/c and in which the ZnII ion exhibits a distorted octahedral coordination by one tetradentate teta ligand and two bridging cyano groups as a trans position, whereas the NiII ion has square planer coordination and is coordinated by four cyano ligands. The decomposition reaction takes places in the temperature range 30–600 °C in the static air atmosphere.
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.200800337