Synthesis and Structures of Dinuclear Copper(I) and Silver(I) 1, 3-Bis[(2-chloro)benzene]triazenide Complexes

In the presence of Et3N, the reaction of 1, 3‐bis[(2‐chloro)benzene]triazene (HL) with CuCl or AgNO3 gives the triazenide complexes {Cu2(L)2} (1) and {Ag2(L)2} (2), respectively. The X‐ray crystal structures of both complexes were obtained. The metal–metal distances (Cu···Cu and Ag···Ag) are 2.4974(...

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Published in:Zeitschrift für anorganische und allgemeine Chemie (1950) 2012-08, Vol.638 (10), p.1519-1522
Main Authors: Cai, Zhan-Mao, Yu, Gang, Lv, Qi-Ying, Jiang, Wen-Qing, Zhan, Shu-Zhong
Format: Article
Language:English
Subjects:
Copper
Crystal structures
Keywords. Triazene
Keywords. Triazene
Copper
Silver
Crystal structures
Metal–metal distances
Metal-metal distances
Silver
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Summary:In the presence of Et3N, the reaction of 1, 3‐bis[(2‐chloro)benzene]triazene (HL) with CuCl or AgNO3 gives the triazenide complexes {Cu2(L)2} (1) and {Ag2(L)2} (2), respectively. The X‐ray crystal structures of both complexes were obtained. The metal–metal distances (Cu···Cu and Ag···Ag) are 2.4974(5) and 2.7208(5) Å, respectively.
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.201200187