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Mechanochemical Synthesis and Characterization of Alkaline Earth Metal Terephthalates: M (C 8 H 4 O 4 )· n H 2 O ( M = Ca, Sr, Ba)
The mechanochemical synthesis offers an easy access to obtain alkaline earth metal terephthalates M (C 8 H 4 O 4 ) · n H 2 O ( M = Ca, Sr, Ba). In the presented study we describe for the first time the mechanochemical synthesis of powders of Ca(C 8 H 4 O 4 ) · 3H 2 O, Ca(C 8 H 4 O 4 ), Sr(C 8 H 4 O...
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| Published in: | Zeitschrift für anorganische und allgemeine Chemie (1950) 2014-02, Vol.640 (2), p.317-324 |
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| Main Authors: | , , |
| Format: | Article |
| Language: | English |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
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| Summary: | The mechanochemical synthesis offers an easy access to obtain alkaline earth metal terephthalates
M
(C
8
H
4
O
4
)
·
n
H
2
O (
M
= Ca, Sr, Ba). In the presented study we describe for the first time the mechanochemical synthesis of powders of Ca(C
8
H
4
O
4
)
·
3H
2
O, Ca(C
8
H
4
O
4
), Sr(C
8
H
4
O
4
)
·
H
2
O, and Ba(C
8
H
4
O
4
), which so far were only synthesized as single crystals from aqueous solutions or by reactions in an autoclave. Furthermore, a new hydrate Ba(C
8
H
4
O
4
)
·
2(1.5)H
2
O, not described so far in the literature, was prepared. All compounds were characterized by X‐ray powder diffraction, thermal analysis, elemental analysis, FT‐IR, and MAS NMR spectroscopic measurements. |
|---|---|
| ISSN: | 0044-2313 1521-3749 |
| DOI: | 10.1002/zaac.201300537 |