Synthesis and Characterization of the New Lacunar Zincophosphate [C 6 H 10 N 2 ][ZnP 2 O 8 H 2 ]·0.6H 2 O

The new zincophosphate of chemical formula [C 6 H 10 N 2 ][ZnP 2 O 8 H 2 ] · 0.6H 2 O was hydrothermally synthesized with p ‐phenylenediamine as structure‐directing agent. The title compound crystallizes in the trigonal symmetry (proposed space group P 3 m 1), where inorganic zincophosphate chains f...

Full description

Saved in:
Bibliographic Details
Published in:Zeitschrift für anorganische und allgemeine Chemie (1950) 2017-12, Vol.643 (22), p.1793-1800
Main Authors: Chouat, Nadjet, Ligner, Emanuelle, Sassi, Mohamed, Hasnaoui, Mohammed Abdelkrim, Michelin, Laure, Josien, Ludovic, Marichal, Claire, Bengueddach, Abdelkader, Patarin, Joël, Paillaud, Jean‐Louis
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The new zincophosphate of chemical formula [C 6 H 10 N 2 ][ZnP 2 O 8 H 2 ] · 0.6H 2 O was hydrothermally synthesized with p ‐phenylenediamine as structure‐directing agent. The title compound crystallizes in the trigonal symmetry (proposed space group P 3 m 1), where inorganic zincophosphate chains form layers due to the half occupancy of the unique crystallographic zinc site. The layers are separated from each other by p ‐phenylenediammonium dications with hydrogen bonding scheme involving the ammonium protons that reveals a pillar‐like 3D structure aspect. The compound was characterized by powder X‐ray diffraction, multinuclear solid‐state NMR, scanning electron microscopy, chemical analysis, and thermogravimetric analysis.
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.201700189