High-Yield Butane to Maleic Anhydride Direct Oxidation on Vanadyl Pyrophosphate Supported on Heat-Conductive Materials: β-SiC, Si3N4, and BN

Both the preparation and the characterization of vanadyl pyrophosphate (VPO) supported on new heat-conductive ceramic supports (β-SiC, Si3N4, and BN) are described. These catalysts provide a very significant gain in maleic anhydride yield by reacting air and butane in a fixed-bed reactor, because of...

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Published in:Journal of catalysis 2001-10, Vol.203 (2), p.495-508
Main Authors: Ledoux, Marc J, Crouzet, Claude, Pham-Huu, Cuong, Turines, Vincent, Kourtakis, Kostantinos, Mills, Patrick L, Lerou, Jan J
Format: Article
Language:English
Subjects:
butane
Catalysis
Catalysts: preparations and properties
Chemistry
Exact sciences and technology
General and physical chemistry
heat-conductive catalyst support
maleic anhydride
oxidation
Si3N4
SiC
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
vanadyl pyrophosphate (VPO)
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container_title Journal of catalysis
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creator Ledoux, Marc J
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Pham-Huu, Cuong
Turines, Vincent
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Lerou, Jan J
description Both the preparation and the characterization of vanadyl pyrophosphate (VPO) supported on new heat-conductive ceramic supports (β-SiC, Si3N4, and BN) are described. These catalysts provide a very significant gain in maleic anhydride yield by reacting air and butane in a fixed-bed reactor, because of control of the catalyst surface temperature. The stable high maleic anhydride selectivity at high temperature, ensured by the presence of the support, allows the use of significantly high partial pressures of butane. In addition, the β-SiC support protects the catalyst against high-temperature accidental excursions.
doi_str_mv 10.1006/jcat.2001.3344
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ispartof Journal of catalysis, 2001-10, Vol.203 (2), p.495-508
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1090-2694
language eng
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subjects butane
Catalysis
Catalysts: preparations and properties
Chemistry
Exact sciences and technology
General and physical chemistry
heat-conductive catalyst support
maleic anhydride
oxidation
Si3N4
SiC
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
vanadyl pyrophosphate (VPO)
title High-Yield Butane to Maleic Anhydride Direct Oxidation on Vanadyl Pyrophosphate Supported on Heat-Conductive Materials: β-SiC, Si3N4, and BN
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