Cyclic Carbonate Synthesis from Supercritical Carbon Dioxide and Epoxide over Lanthanide Oxychloride

Lanthanide oxychloride, especially SmOCl, is an efficient solid catalyst for propylene carbonate synthesis from supercritical CO2 and propylene oxide. The process requires no additional organic solvents and the product is automatically separated out from the CO2 phase.

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Bibliographic Details
Published in:Journal of catalysis 2002-07, Vol.209 (2), p.547-550
Main Authors: Yasuda, Hiroyuki, He, Liang-Nian, Sakakura, Toshiyasu
Format: Article
Language:English
Subjects:
Catalysis
Catalytic reactions
Chemistry
Exact sciences and technology
General and physical chemistry
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Description
Summary:Lanthanide oxychloride, especially SmOCl, is an efficient solid catalyst for propylene carbonate synthesis from supercritical CO2 and propylene oxide. The process requires no additional organic solvents and the product is automatically separated out from the CO2 phase.
ISSN:0021-9517
1090-2694
DOI:10.1006/jcat.2002.3662