Densities, speeds of sound, and isentropic compressibilities of a cyclic ether with chlorocyclohexane, or bromocyclohexane at the temperatures 298.15 K and 313.15 K

Isentropic compressibilities κSand excess isentropic compressibilities κESof {xC4H8O, orxC5H10O, orx(CH3)C4H7O, orx(CH3)2C4H6O+(1−x)C6H11Cl, or (1−x)C6H11Br} were calculated from measured density and speed of sound measurements atT=(298.15 and 313.15) K. The excess isentropic compressibilities were...

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Bibliographic Details
Published in:The Journal of chemical thermodynamics 1999-01, Vol.31 (1), p.139-149
Main Authors: Rodrı́guez, S., Lafuente, C., Artigas, H., Royo, F.M., Urieta, J.S.
Format: Article
Language:English
Subjects:
binary mixtures
bromocyclohexane
Chemical thermodynamics
Chemistry
chlorocyclohexane
cyclic ethers
Exact sciences and technology
General and physical chemistry
isentropic compressibilities
Mixtures
Thermodynamic properties
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Summary:Isentropic compressibilities κSand excess isentropic compressibilities κESof {xC4H8O, orxC5H10O, orx(CH3)C4H7O, orx(CH3)2C4H6O+(1−x)C6H11Cl, or (1−x)C6H11Br} were calculated from measured density and speed of sound measurements atT=(298.15 and 313.15) K. The excess isentropic compressibilities were fitted to the Redlich–Kister equation. The mixtures studied show large negative values for κES.
ISSN:0021-9614
1096-3626
DOI:10.1006/jcht.1998.0437