Thermodynamic study on the sublimation of 1,2-diphenylethane and of 3-phenylpropiolic acid

The Knudsen mass-loss effusion technique was used to measure the vapour pressures at different temperatures of the following crystalline compounds: 1,2-diphenylethane (bibenzyl), between T= 289.16 K and T= 303.20 K, and of 3-phenylpropiolic acid between T= 329.15 K and T= 343.15 K. From the temperat...

Full description

Saved in:
Bibliographic Details
Published in:The Journal of chemical thermodynamics 2001-08, Vol.33 (8), p.849-857
Main Authors: Monte, Manuel J.S., Hillesheim, Dorothea M.
Format: Article
Language:English
Subjects:
1,2-diphenylethane
3-phenylpropiolic acid
bibenzyl
Chemical thermodynamics
Chemistry
Elements, mineral and organic compounds
enthalpies of sublimation
entropies of sublimation
Exact sciences and technology
General and physical chemistry
standard Gibbs energies of sublimation
Thermodynamic properties
vapour pressures
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c382t-ed197c52e804b8ad00b35bdbf1f6de7bc474847f385ea3c8263148eded7199393
cites cdi_FETCH-LOGICAL-c382t-ed197c52e804b8ad00b35bdbf1f6de7bc474847f385ea3c8263148eded7199393
container_end_page 857
container_issue 8
container_start_page 849
container_title The Journal of chemical thermodynamics
container_volume 33
creator Monte, Manuel J.S.
Hillesheim, Dorothea M.
description The Knudsen mass-loss effusion technique was used to measure the vapour pressures at different temperatures of the following crystalline compounds: 1,2-diphenylethane (bibenzyl), between T= 289.16 K and T= 303.20 K, and of 3-phenylpropiolic acid between T= 329.15 K and T= 343.15 K. From the temperature dependence of the vapour pressure, the standard molar enthalpies of sublimation at the mean temperature of the experimental range were derived by the Clausius–Clapeyron equation. From these results the standard, po= 105Pa, molar enthalpies, entropies, and Gibbs energies of sublimation at T= 298.15 K, were calculated:
doi_str_mv 10.1006/jcht.2000.0761
format article
fullrecord <record><control><sourceid>elsevier_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1006_jcht_2000_0761</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0021961400907614</els_id><sourcerecordid>S0021961400907614</sourcerecordid><originalsourceid>FETCH-LOGICAL-c382t-ed197c52e804b8ad00b35bdbf1f6de7bc474847f385ea3c8263148eded7199393</originalsourceid><addsrcrecordid>eNp1ULFOwzAQtRBIlMLKnIWNhHPsOs6IKihIlVjKwmI59kVxlSaR7SLl70kUJCam09299-7dI-SeQkYBxNPRNDHLASCDQtALsqJQipSJXFySFUBO01JQfk1uQjhOqJKVsCJfhwb9qbdjp0_OJCGe7Zj0XRIbTMK5at1JRzf1fZ3Qxzy1bmiwG1uMje4w0Z2dNyxdpoPvB9e3k442zt6Sq1q3Ae9-65p8vr4ctm_p_mP3vn3ep4bJPKZoaVmYTY4SeCW1BajYprJVTWthsagML7jkRc3kBjUzMheMcokWbUHL6Qm2Jtmia3wfgsdaDX6y7UdFQc3JqDkZNSej5mQmwsNCGHQwuq297owLfyxOGed0FpYLDif33w69CsZhZ9A6jyYq27v_TvwAu5J3-w</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Thermodynamic study on the sublimation of 1,2-diphenylethane and of 3-phenylpropiolic acid</title><source>ScienceDirect Freedom Collection</source><creator>Monte, Manuel J.S. ; Hillesheim, Dorothea M.</creator><creatorcontrib>Monte, Manuel J.S. ; Hillesheim, Dorothea M.</creatorcontrib><description>The Knudsen mass-loss effusion technique was used to measure the vapour pressures at different temperatures of the following crystalline compounds: 1,2-diphenylethane (bibenzyl), between T= 289.16 K and T= 303.20 K, and of 3-phenylpropiolic acid between T= 329.15 K and T= 343.15 K. From the temperature dependence of the vapour pressure, the standard molar enthalpies of sublimation at the mean temperature of the experimental range were derived by the Clausius–Clapeyron equation. From these results the standard, po= 105Pa, molar enthalpies, entropies, and Gibbs energies of sublimation at T= 298.15 K, were calculated:</description><identifier>ISSN: 0021-9614</identifier><identifier>EISSN: 1096-3626</identifier><identifier>DOI: 10.1006/jcht.2000.0761</identifier><identifier>CODEN: JCTDAF</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>1,2-diphenylethane ; 3-phenylpropiolic acid ; bibenzyl ; Chemical thermodynamics ; Chemistry ; Elements, mineral and organic compounds ; enthalpies of sublimation ; entropies of sublimation ; Exact sciences and technology ; General and physical chemistry ; standard Gibbs energies of sublimation ; Thermodynamic properties ; vapour pressures</subject><ispartof>The Journal of chemical thermodynamics, 2001-08, Vol.33 (8), p.849-857</ispartof><rights>2001 Academic Press</rights><rights>2002 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c382t-ed197c52e804b8ad00b35bdbf1f6de7bc474847f385ea3c8263148eded7199393</citedby><cites>FETCH-LOGICAL-c382t-ed197c52e804b8ad00b35bdbf1f6de7bc474847f385ea3c8263148eded7199393</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=14134419$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Monte, Manuel J.S.</creatorcontrib><creatorcontrib>Hillesheim, Dorothea M.</creatorcontrib><title>Thermodynamic study on the sublimation of 1,2-diphenylethane and of 3-phenylpropiolic acid</title><title>The Journal of chemical thermodynamics</title><description>The Knudsen mass-loss effusion technique was used to measure the vapour pressures at different temperatures of the following crystalline compounds: 1,2-diphenylethane (bibenzyl), between T= 289.16 K and T= 303.20 K, and of 3-phenylpropiolic acid between T= 329.15 K and T= 343.15 K. From the temperature dependence of the vapour pressure, the standard molar enthalpies of sublimation at the mean temperature of the experimental range were derived by the Clausius–Clapeyron equation. From these results the standard, po= 105Pa, molar enthalpies, entropies, and Gibbs energies of sublimation at T= 298.15 K, were calculated:</description><subject>1,2-diphenylethane</subject><subject>3-phenylpropiolic acid</subject><subject>bibenzyl</subject><subject>Chemical thermodynamics</subject><subject>Chemistry</subject><subject>Elements, mineral and organic compounds</subject><subject>enthalpies of sublimation</subject><subject>entropies of sublimation</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>standard Gibbs energies of sublimation</subject><subject>Thermodynamic properties</subject><subject>vapour pressures</subject><issn>0021-9614</issn><issn>1096-3626</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><recordid>eNp1ULFOwzAQtRBIlMLKnIWNhHPsOs6IKihIlVjKwmI59kVxlSaR7SLl70kUJCam09299-7dI-SeQkYBxNPRNDHLASCDQtALsqJQipSJXFySFUBO01JQfk1uQjhOqJKVsCJfhwb9qbdjp0_OJCGe7Zj0XRIbTMK5at1JRzf1fZ3Qxzy1bmiwG1uMje4w0Z2dNyxdpoPvB9e3k442zt6Sq1q3Ae9-65p8vr4ctm_p_mP3vn3ep4bJPKZoaVmYTY4SeCW1BajYprJVTWthsagML7jkRc3kBjUzMheMcokWbUHL6Qm2Jtmia3wfgsdaDX6y7UdFQc3JqDkZNSej5mQmwsNCGHQwuq297owLfyxOGed0FpYLDif33w69CsZhZ9A6jyYq27v_TvwAu5J3-w</recordid><startdate>20010801</startdate><enddate>20010801</enddate><creator>Monte, Manuel J.S.</creator><creator>Hillesheim, Dorothea M.</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20010801</creationdate><title>Thermodynamic study on the sublimation of 1,2-diphenylethane and of 3-phenylpropiolic acid</title><author>Monte, Manuel J.S. ; Hillesheim, Dorothea M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c382t-ed197c52e804b8ad00b35bdbf1f6de7bc474847f385ea3c8263148eded7199393</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><topic>1,2-diphenylethane</topic><topic>3-phenylpropiolic acid</topic><topic>bibenzyl</topic><topic>Chemical thermodynamics</topic><topic>Chemistry</topic><topic>Elements, mineral and organic compounds</topic><topic>enthalpies of sublimation</topic><topic>entropies of sublimation</topic><topic>Exact sciences and technology</topic><topic>General and physical chemistry</topic><topic>standard Gibbs energies of sublimation</topic><topic>Thermodynamic properties</topic><topic>vapour pressures</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Monte, Manuel J.S.</creatorcontrib><creatorcontrib>Hillesheim, Dorothea M.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>The Journal of chemical thermodynamics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Monte, Manuel J.S.</au><au>Hillesheim, Dorothea M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermodynamic study on the sublimation of 1,2-diphenylethane and of 3-phenylpropiolic acid</atitle><jtitle>The Journal of chemical thermodynamics</jtitle><date>2001-08-01</date><risdate>2001</risdate><volume>33</volume><issue>8</issue><spage>849</spage><epage>857</epage><pages>849-857</pages><issn>0021-9614</issn><eissn>1096-3626</eissn><coden>JCTDAF</coden><abstract>The Knudsen mass-loss effusion technique was used to measure the vapour pressures at different temperatures of the following crystalline compounds: 1,2-diphenylethane (bibenzyl), between T= 289.16 K and T= 303.20 K, and of 3-phenylpropiolic acid between T= 329.15 K and T= 343.15 K. From the temperature dependence of the vapour pressure, the standard molar enthalpies of sublimation at the mean temperature of the experimental range were derived by the Clausius–Clapeyron equation. From these results the standard, po= 105Pa, molar enthalpies, entropies, and Gibbs energies of sublimation at T= 298.15 K, were calculated:</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1006/jcht.2000.0761</doi><tpages>9</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0021-9614
ispartof The Journal of chemical thermodynamics, 2001-08, Vol.33 (8), p.849-857
issn 0021-9614
1096-3626
language eng
recordid cdi_crossref_primary_10_1006_jcht_2000_0761
source ScienceDirect Freedom Collection
subjects 1,2-diphenylethane
3-phenylpropiolic acid
bibenzyl
Chemical thermodynamics
Chemistry
Elements, mineral and organic compounds
enthalpies of sublimation
entropies of sublimation
Exact sciences and technology
General and physical chemistry
standard Gibbs energies of sublimation
Thermodynamic properties
vapour pressures
title Thermodynamic study on the sublimation of 1,2-diphenylethane and of 3-phenylpropiolic acid
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-27T00%3A38%3A59IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-elsevier_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Thermodynamic%20study%20on%20the%20sublimation%20of%201,2-diphenylethane%20and%20of%203-phenylpropiolic%20acid&rft.jtitle=The%20Journal%20of%20chemical%20thermodynamics&rft.au=Monte,%20Manuel%20J.S.&rft.date=2001-08-01&rft.volume=33&rft.issue=8&rft.spage=849&rft.epage=857&rft.pages=849-857&rft.issn=0021-9614&rft.eissn=1096-3626&rft.coden=JCTDAF&rft_id=info:doi/10.1006/jcht.2000.0761&rft_dat=%3Celsevier_cross%3ES0021961400907614%3C/elsevier_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c382t-ed197c52e804b8ad00b35bdbf1f6de7bc474847f385ea3c8263148eded7199393%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true