Experimental determination of the enthalpy of formation of dibenzo- p-dioxin

The standard molar enthalpy of combustion of dibenzo- p -dioxin (DD) was measured at T= 298.15 K by static-bomb combustion calorimetry: ΔcHmo(cr) =−(5723.8 ± 1.4)kJ · mol−1. The standard molar enthalpy of sublimation of this compound was measured by microcalorimetry: ΔcrgHmo= (91.45 ± 0.76)kJ · mol−...

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Published in:The Journal of chemical thermodynamics 2002-03, Vol.34 (3), p.385-390
Main Authors: Pimenova, S.M., Melkhanova, S.V., Kolesov, V.P., Demyanov, P.I., Fedotov, A.N., Vorobieva, V.P.
Format: Article
Language:English
Subjects:
calorimetry
dibenzodioxins
enthalpies of combustion
enthalpies of formation
environmental protection
thermochemistry
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container_title The Journal of chemical thermodynamics
container_volume 34
creator Pimenova, S.M.
Melkhanova, S.V.
Kolesov, V.P.
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Fedotov, A.N.
Vorobieva, V.P.
description The standard molar enthalpy of combustion of dibenzo- p -dioxin (DD) was measured at T= 298.15 K by static-bomb combustion calorimetry: ΔcHmo(cr) =−(5723.8 ± 1.4)kJ · mol−1. The standard molar enthalpy of sublimation of this compound was measured by microcalorimetry: ΔcrgHmo= (91.45 ± 0.76)kJ · mol−1. These values were used to derive the standard molar enthalpies of formation of DD in the crystalline and gaseous states: ΔfHmo(cr) =−(141.6 ± 2.1)kJ · mol−1and ΔfHmo(g) =−(50.1 ± 2.2)kJ · mol−1. The specially obtained sample of DD of high purity {mole fraction x= (0.9999 ± 0.0001)} was used in all measurements.
doi_str_mv 10.1006/jcht.2001.0951
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subjects calorimetry
dibenzodioxins
enthalpies of combustion
enthalpies of formation
environmental protection
thermochemistry
title Experimental determination of the enthalpy of formation of dibenzo- p-dioxin
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