Microwave Spectrum, Dipole Moment, and Conformation of Methyl Vinyl Sulfone

The microwave spectrum of methyl vinyl sulfone, CH 2CHSO 2CH 3, has been investigated in the frequency region 26.5 to 40 GHz. The assigned transitions are consistent with a conformation in which one of the SO bonds nearly eclipses the CC bond. This eclipsed conformer has been found to be at least...

Full description

Saved in:
Bibliographic Details
Published in:Journal of molecular spectroscopy 1994-04, Vol.164 (2), p.319-327
Main Authors: Fantoni, A.C., Corbelli, G.
Format: Article
Language:English
Subjects:
Atomic and molecular physics
Conformation (statistics and dynamics)
Electric and magnetic moments (and derivatives), polarizability, and magnetic susceptibility
Exact sciences and technology
Macromolecules and polymer molecules
Molecular properties and interactions with photons
Molecular spectra
Physics
Radio-frequency and microwave spectra
Rotation, vibration, and vibration-rotation constants
Studies of special atoms, molecules and their ions
clusters
Citations: Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c315t-5d0188e89b350ac0649ea8dcf281fa691b5565ba4671703105dc85b3cb29f4f53
cites
container_end_page 327
container_issue 2
container_start_page 319
container_title Journal of molecular spectroscopy
container_volume 164
creator Fantoni, A.C.
Corbelli, G.
description The microwave spectrum of methyl vinyl sulfone, CH 2CHSO 2CH 3, has been investigated in the frequency region 26.5 to 40 GHz. The assigned transitions are consistent with a conformation in which one of the SO bonds nearly eclipses the CC bond. This eclipsed conformer has been found to be at least 0.7 kcal/mole more stable than the s- cis form. From the second-order Stark effect measurements the electric dipole moment has been determined. A lower limit of 2800 cal/mole has been established for the V 3 barrier to the methyl group internal rotation.
doi_str_mv 10.1006/jmsp.1994.1077
format article
fullrecord <record><control><sourceid>elsevier_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1006_jmsp_1994_1077</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0022285284710770</els_id><sourcerecordid>S0022285284710770</sourcerecordid><originalsourceid>FETCH-LOGICAL-c315t-5d0188e89b350ac0649ea8dcf281fa691b5565ba4671703105dc85b3cb29f4f53</originalsourceid><addsrcrecordid>eNp1kL1PwzAQxS0EEuVjZfbASMpdEifOiMqnaMVQQGyW49jCVWJHdijqf0-iIjaWezrpvbunHyEXCHMEKK43XeznWFX5uJblAZkhVEUCPPs4JDOANE1SztJjchLjBgCRldmMPK-sCv5bbjVd91oN4au7ore2962mK99pN1xR6Rq68M740MnBeke9oSs9fO5a-m7dONdfrfFOn5EjI9uoz3_1lLzd370uHpPly8PT4maZqAzZkLAGkHPNqzpjIBUUeaUlb5RJORpZVFgzVrBa5kWJJWQIrFGc1Zmq08rkhmWnZL6_OzaPMWgj-mA7GXYCQUwoxIRCTCjEhGIMXO4DvYxKtiZIp2z8S-WQF4iTje9teiy_tTqIqKx2Sjc2jGhE4-1_H34A-etx8A</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Microwave Spectrum, Dipole Moment, and Conformation of Methyl Vinyl Sulfone</title><source>ScienceDirect: Physics General Backfile</source><creator>Fantoni, A.C. ; Corbelli, G.</creator><creatorcontrib>Fantoni, A.C. ; Corbelli, G.</creatorcontrib><description>The microwave spectrum of methyl vinyl sulfone, CH 2CHSO 2CH 3, has been investigated in the frequency region 26.5 to 40 GHz. The assigned transitions are consistent with a conformation in which one of the SO bonds nearly eclipses the CC bond. This eclipsed conformer has been found to be at least 0.7 kcal/mole more stable than the s- cis form. From the second-order Stark effect measurements the electric dipole moment has been determined. A lower limit of 2800 cal/mole has been established for the V 3 barrier to the methyl group internal rotation.</description><identifier>ISSN: 0022-2852</identifier><identifier>EISSN: 1096-083X</identifier><identifier>DOI: 10.1006/jmsp.1994.1077</identifier><identifier>CODEN: JMOSA3</identifier><language>eng</language><publisher>San Diego, CA: Elsevier Inc</publisher><subject>Atomic and molecular physics ; Conformation (statistics and dynamics) ; Electric and magnetic moments (and derivatives), polarizability, and magnetic susceptibility ; Exact sciences and technology ; Macromolecules and polymer molecules ; Molecular properties and interactions with photons ; Molecular spectra ; Physics ; Radio-frequency and microwave spectra ; Rotation, vibration, and vibration-rotation constants ; Studies of special atoms, molecules and their ions; clusters</subject><ispartof>Journal of molecular spectroscopy, 1994-04, Vol.164 (2), p.319-327</ispartof><rights>1994 Academic Press</rights><rights>1994 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c315t-5d0188e89b350ac0649ea8dcf281fa691b5565ba4671703105dc85b3cb29f4f53</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0022285284710770$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3619,27901,27902,45987</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=4046117$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Fantoni, A.C.</creatorcontrib><creatorcontrib>Corbelli, G.</creatorcontrib><title>Microwave Spectrum, Dipole Moment, and Conformation of Methyl Vinyl Sulfone</title><title>Journal of molecular spectroscopy</title><description>The microwave spectrum of methyl vinyl sulfone, CH 2CHSO 2CH 3, has been investigated in the frequency region 26.5 to 40 GHz. The assigned transitions are consistent with a conformation in which one of the SO bonds nearly eclipses the CC bond. This eclipsed conformer has been found to be at least 0.7 kcal/mole more stable than the s- cis form. From the second-order Stark effect measurements the electric dipole moment has been determined. A lower limit of 2800 cal/mole has been established for the V 3 barrier to the methyl group internal rotation.</description><subject>Atomic and molecular physics</subject><subject>Conformation (statistics and dynamics)</subject><subject>Electric and magnetic moments (and derivatives), polarizability, and magnetic susceptibility</subject><subject>Exact sciences and technology</subject><subject>Macromolecules and polymer molecules</subject><subject>Molecular properties and interactions with photons</subject><subject>Molecular spectra</subject><subject>Physics</subject><subject>Radio-frequency and microwave spectra</subject><subject>Rotation, vibration, and vibration-rotation constants</subject><subject>Studies of special atoms, molecules and their ions; clusters</subject><issn>0022-2852</issn><issn>1096-083X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1994</creationdate><recordtype>article</recordtype><recordid>eNp1kL1PwzAQxS0EEuVjZfbASMpdEifOiMqnaMVQQGyW49jCVWJHdijqf0-iIjaWezrpvbunHyEXCHMEKK43XeznWFX5uJblAZkhVEUCPPs4JDOANE1SztJjchLjBgCRldmMPK-sCv5bbjVd91oN4au7ore2962mK99pN1xR6Rq68M740MnBeke9oSs9fO5a-m7dONdfrfFOn5EjI9uoz3_1lLzd370uHpPly8PT4maZqAzZkLAGkHPNqzpjIBUUeaUlb5RJORpZVFgzVrBa5kWJJWQIrFGc1Zmq08rkhmWnZL6_OzaPMWgj-mA7GXYCQUwoxIRCTCjEhGIMXO4DvYxKtiZIp2z8S-WQF4iTje9teiy_tTqIqKx2Sjc2jGhE4-1_H34A-etx8A</recordid><startdate>19940401</startdate><enddate>19940401</enddate><creator>Fantoni, A.C.</creator><creator>Corbelli, G.</creator><general>Elsevier Inc</general><general>Elsevier</general><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19940401</creationdate><title>Microwave Spectrum, Dipole Moment, and Conformation of Methyl Vinyl Sulfone</title><author>Fantoni, A.C. ; Corbelli, G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c315t-5d0188e89b350ac0649ea8dcf281fa691b5565ba4671703105dc85b3cb29f4f53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1994</creationdate><topic>Atomic and molecular physics</topic><topic>Conformation (statistics and dynamics)</topic><topic>Electric and magnetic moments (and derivatives), polarizability, and magnetic susceptibility</topic><topic>Exact sciences and technology</topic><topic>Macromolecules and polymer molecules</topic><topic>Molecular properties and interactions with photons</topic><topic>Molecular spectra</topic><topic>Physics</topic><topic>Radio-frequency and microwave spectra</topic><topic>Rotation, vibration, and vibration-rotation constants</topic><topic>Studies of special atoms, molecules and their ions; clusters</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fantoni, A.C.</creatorcontrib><creatorcontrib>Corbelli, G.</creatorcontrib><collection>Pascal-Francis</collection><collection>CrossRef</collection><jtitle>Journal of molecular spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fantoni, A.C.</au><au>Corbelli, G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Microwave Spectrum, Dipole Moment, and Conformation of Methyl Vinyl Sulfone</atitle><jtitle>Journal of molecular spectroscopy</jtitle><date>1994-04-01</date><risdate>1994</risdate><volume>164</volume><issue>2</issue><spage>319</spage><epage>327</epage><pages>319-327</pages><issn>0022-2852</issn><eissn>1096-083X</eissn><coden>JMOSA3</coden><abstract>The microwave spectrum of methyl vinyl sulfone, CH 2CHSO 2CH 3, has been investigated in the frequency region 26.5 to 40 GHz. The assigned transitions are consistent with a conformation in which one of the SO bonds nearly eclipses the CC bond. This eclipsed conformer has been found to be at least 0.7 kcal/mole more stable than the s- cis form. From the second-order Stark effect measurements the electric dipole moment has been determined. A lower limit of 2800 cal/mole has been established for the V 3 barrier to the methyl group internal rotation.</abstract><cop>San Diego, CA</cop><pub>Elsevier Inc</pub><doi>10.1006/jmsp.1994.1077</doi><tpages>9</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0022-2852
ispartof Journal of molecular spectroscopy, 1994-04, Vol.164 (2), p.319-327
issn 0022-2852
1096-083X
language eng
recordid cdi_crossref_primary_10_1006_jmsp_1994_1077
source ScienceDirect: Physics General Backfile
subjects Atomic and molecular physics
Conformation (statistics and dynamics)
Electric and magnetic moments (and derivatives), polarizability, and magnetic susceptibility
Exact sciences and technology
Macromolecules and polymer molecules
Molecular properties and interactions with photons
Molecular spectra
Physics
Radio-frequency and microwave spectra
Rotation, vibration, and vibration-rotation constants
Studies of special atoms, molecules and their ions
clusters
title Microwave Spectrum, Dipole Moment, and Conformation of Methyl Vinyl Sulfone
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-13T03%3A59%3A27IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-elsevier_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Microwave%20Spectrum,%20Dipole%20Moment,%20and%20Conformation%20of%20Methyl%20Vinyl%20Sulfone&rft.jtitle=Journal%20of%20molecular%20spectroscopy&rft.au=Fantoni,%20A.C.&rft.date=1994-04-01&rft.volume=164&rft.issue=2&rft.spage=319&rft.epage=327&rft.pages=319-327&rft.issn=0022-2852&rft.eissn=1096-083X&rft.coden=JMOSA3&rft_id=info:doi/10.1006/jmsp.1994.1077&rft_dat=%3Celsevier_cross%3ES0022285284710770%3C/elsevier_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c315t-5d0188e89b350ac0649ea8dcf281fa691b5565ba4671703105dc85b3cb29f4f53%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true