Rotational Spectrum, Molecular Constants, and Dipole Moment of theSynForm of Vinylphosphine

The rotational spectrum of thesynconformer of vinylphosphine from 8 to 250 GHz has been measured. The assignment was based onab initiocalculations performed at the MP2 level using the 6-311G (2d,p) basis set. Rotational and centrifugal distortion constants up to the sextic terms were determined. The...

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Bibliographic Details
Published in:Journal of molecular spectroscopy 1996-03, Vol.176 (1), p.180-184
Main Authors: Dréan, Pascal, Colmont, Jean-Marcel, Lesarri, Alberto, López, Juan Carlos
Format: Article
Language:English
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Summary:The rotational spectrum of thesynconformer of vinylphosphine from 8 to 250 GHz has been measured. The assignment was based onab initiocalculations performed at the MP2 level using the 6-311G (2d,p) basis set. Rotational and centrifugal distortion constants up to the sextic terms were determined. The dipole moment was measured using the Stark effect. It is to be noted that theab initiostructure reproduces the experimental data satisfactorily.
ISSN:0022-2852
1096-083X
DOI:10.1006/jmsp.1996.0075