Microwave Spectroscopy of Vinyl Cyanide, Taking into Account the Hyperfine Structure

New measurements of the rotational spectrum of vinyl cyanide in the ground vibrational state were obtained within the range 55 to 155 GHz. In total, 204 frequencies were measured. The range of the quantum numbers is 2 ≤J≤ 78, 0 ≤K−1≤ 15. The accuracy of measurements is better than 10 kHz. A more pre...

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Published in:Journal of molecular spectroscopy 1996-09, Vol.179 (1), p.94-98
Main Authors: Baskakov, O.I., Dyubko, S.F., Ilyushin, V.V., Efimenko, M.N., Efremov, V.A., Podnos, S.V., Alekseev, E.A.
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container_issue 1
container_start_page 94
container_title Journal of molecular spectroscopy
container_volume 179
creator Baskakov, O.I.
Dyubko, S.F.
Ilyushin, V.V.
Efimenko, M.N.
Efremov, V.A.
Podnos, S.V.
Alekseev, E.A.
description New measurements of the rotational spectrum of vinyl cyanide in the ground vibrational state were obtained within the range 55 to 155 GHz. In total, 204 frequencies were measured. The range of the quantum numbers is 2 ≤J≤ 78, 0 ≤K−1≤ 15. The accuracy of measurements is better than 10 kHz. A more precise set of rotational and centrifugal distortion parameters was found by taking into account the hyperfine quadrupole splitting. The standard deviation for the fit was 3.7 kHz.
doi_str_mv 10.1006/jmsp.1996.0188
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title Microwave Spectroscopy of Vinyl Cyanide, Taking into Account the Hyperfine Structure
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