Solid State Synthesis of Mo(W)-S Cluster Compounds at Low Heating Temperatures

A new method for synthesis of Mo(W)-S cluster compounds by solid state reactions at low heating temperatures is introduced. The factors which may influence solid state reactions are discussed. Over twenty novel structurally characterized Mo(W)-S cluster compounds including the big mixed-metal cluste...

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Bibliographic Details
Published in:Journal of solid state chemistry 1994, Vol.108 (1), p.118-127
Main Authors: Jianping, Lang, Xinquan, Xin
Format: Article
Language:English
Subjects:
Chemistry
Condensed matter: structure, mechanical and thermal properties
Coordination compounds
Exact sciences and technology
Inorganic chemistry and origins of life
Inorganic compounds
Metal complexes
Physics
Preparations and properties
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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Summary:A new method for synthesis of Mo(W)-S cluster compounds by solid state reactions at low heating temperatures is introduced. The factors which may influence solid state reactions are discussed. Over twenty novel structurally characterized Mo(W)-S cluster compounds including the big mixed-metal cluster compound [( n - Bu) 4] 4[Mo 8Cu 12S 32] are summarized.
ISSN:0022-4596
1095-726X
DOI:10.1006/jssc.1994.1018