Two-cell detonation: losses effects on cellular structure and propagation in rich H2–NO2/N2O4–Ar mixtures

• Published in: Shock waves 2010-12, Vol.20 (6), p.457-465
• Main Authors: Virot, F., Khasainov, B., Desbordes, D., Presles, H.-N.
• Format: Article
• Language: English
• Subjects: Acoustics; Condensed Matter Physics; Engineering; Engineering Fluid Dynamics; Engineering Thermodynamics; Fluid- and Aerodynamics; Heat and Mass Transfer; Original Article; Thermodynamics
• ISSN: 0938-1287; 1432-2153
• DOI: 10.1007/s00193-010-0283-x

Detonation experiments in H 2 –NO 2 /N 2 O 4 –Ar mixtures (Equivalence ratio 1.2 and initial pressure lower than 0.1 MPa) confined in a tube of internal diameter 52 mm reveal two propagation regimes depending on initial pressure: (1) a quasi-CJ regime is observed along with a double cellular structure at high pressures; (2) at lower pressures, a low velocity detonation regime is observed with a single structure. Transition between this two regimes happens when the spinning detonation of the larger cell vanishes. Each detonation regime is characterized by velocity and pressure measurements and cellular structure records. Coherence between all experimental data for each experiment leads in assumption that losses are responsible for the transition between one regime to another. In a second part, we study such behaviour for a two-step mixture through numerical simulations using a global two-step chemical kinetics and a simple losses model. Numerical simulations qualitatively agree with experiments. Both detonation regimes with their own cellular structures are reproduced.