The dehydration process of gypsum under high pressure

• Published in: Physics and chemistry of minerals 2012, Vol.39 (1), p.65-71
• Main Authors: Comodi, P., Kurnosov, A., Nazzareni, S., Dubrovinsky, L.
• Format: Article
• Language: English
• Subjects: Crystallography and Scattering Methods; Earth and Environmental Science; Earth Sciences; Geochemistry; Mineral Resources; Mineralogy
• ISSN: 0342-1791; 1432-2021
• DOI: 10.1007/s00269-011-0460-1

The effects of pressure on the dehydration of gypsum materials were investigated up to 633 K and 25 GPa by using Raman spectroscopy and synchrotron X-ray diffraction with an externally heated diamond anvil cell. At 2.5 GPa, gypsum starts to dehydrate around 428 K, by forming bassanite, CaSO 4 hemihydrate, which completely dehydrates to γ-anhydrite at 488 K. All the sulphate modes decrease linearly between 293 and 427 K with temperature coefficients ranging from −0.119 to −0.021 cm −1 K −1 , where an abrupt change in the ν 3 mode and in the OH-stretching region indicates the beginning of dehydration. Increasing the temperature to 488 K, the OH-stretching modes completely disappear, marking the complete dehydration and formation of γ-anhydrite. Moreover, the sample changes from transparent to opaque to transparent again during the dehydration sequence gypsum-bassanite-γ-anhydrite, which irreversibly transforms to β-anhydrite form at 593 K. These data compared with the dehydration temperature at room pressure indicate that the dehydration temperature increases with pressure with a Δ P /Δ T slope equal to 230 bar/K. Synchrotron X-ray diffraction experiments show similar values of temperature and pressure for the first appearance of bassanite. Evidence of phase transition from β-anhydrite structure to the monazite type was observed at about 2 GPa under cold compression. On the other hand at the same pressure (2 GPa and 633 K), β-anhydrite was found, indicating a positive Clausis-Clayperon slope of the transition. This transformation is completely reversible as showed by the Raman spectra on the sample recovered after phase transition.