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One-step preparation of the BiVO4 film photoelectrode
A one-step method of preparing photoelectrochemically active nanostructured BiVO 4 films is reported based on thermolysis (500 °C in air) of a polyethylene glycol (PEG300) “paint-on” precursor solution containing Bi 3+ (as nitrate) and VO 4 3− (as the metavanadate ammonium salt). Films are formed di...
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| Published in: | Journal of solid state electrochemistry 2015-01, Vol.19 (1), p.31-35 |
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| Main Authors: | , , , , , , , , , , |
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| Language: | English |
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| container_end_page | 35 |
| container_issue | 1 |
| container_start_page | 31 |
| container_title | Journal of solid state electrochemistry |
| container_volume | 19 |
| creator | Mascaro, Lucia H. Pockett, Adam Mitchels, John M. Peter, Laurence M. Cameron, Petra J. Celorrio, Veronica Fermin, David J. Sagu, Jagdeep S. Wijayantha, K. G. Upul Kociok-Köhn, Gabriele Marken, Frank |
| description | A one-step method of preparing photoelectrochemically active nanostructured BiVO
4
films is reported based on thermolysis (500 °C in air) of a polyethylene glycol (PEG300) “paint-on” precursor solution containing Bi
3+
(as nitrate) and VO
4
3−
(as the metavanadate ammonium salt). Films are formed directly on tin-doped indium oxide (ITO) substrates and characterised by electron microscopy (scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS)), X-ray diffraction, Raman spectroscopy, and photoelectrochemistry. The nanocrystalline film exhibited typically up to 52 % incident photon to current efficiency (IPCE) at 1.0 V vs. saturated calomel electrode (SCE) in aqueous 0.5 M Na
2
SO
4
with oxalate, strongly enhancing photocurrents.
Figure
Coloured FE-SEM image |
| doi_str_mv | 10.1007/s10008-014-2495-y |
| format | article |
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4
films is reported based on thermolysis (500 °C in air) of a polyethylene glycol (PEG300) “paint-on” precursor solution containing Bi
3+
(as nitrate) and VO
4
3−
(as the metavanadate ammonium salt). Films are formed directly on tin-doped indium oxide (ITO) substrates and characterised by electron microscopy (scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS)), X-ray diffraction, Raman spectroscopy, and photoelectrochemistry. The nanocrystalline film exhibited typically up to 52 % incident photon to current efficiency (IPCE) at 1.0 V vs. saturated calomel electrode (SCE) in aqueous 0.5 M Na
2
SO
4
with oxalate, strongly enhancing photocurrents.
Figure
Coloured FE-SEM image</description><identifier>ISSN: 1432-8488</identifier><identifier>EISSN: 1433-0768</identifier><identifier>DOI: 10.1007/s10008-014-2495-y</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Analytical Chemistry ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Electrochemistry ; Energy Storage ; Original Paper ; Physical Chemistry</subject><ispartof>Journal of solid state electrochemistry, 2015-01, Vol.19 (1), p.31-35</ispartof><rights>Springer-Verlag Berlin Heidelberg 2014</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c399t-a22b4a91d90c3793617489dce7b16ddc459ecd5845fac2e2e1175b93d76c4afe3</citedby><cites>FETCH-LOGICAL-c399t-a22b4a91d90c3793617489dce7b16ddc459ecd5845fac2e2e1175b93d76c4afe3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Mascaro, Lucia H.</creatorcontrib><creatorcontrib>Pockett, Adam</creatorcontrib><creatorcontrib>Mitchels, John M.</creatorcontrib><creatorcontrib>Peter, Laurence M.</creatorcontrib><creatorcontrib>Cameron, Petra J.</creatorcontrib><creatorcontrib>Celorrio, Veronica</creatorcontrib><creatorcontrib>Fermin, David J.</creatorcontrib><creatorcontrib>Sagu, Jagdeep S.</creatorcontrib><creatorcontrib>Wijayantha, K. G. Upul</creatorcontrib><creatorcontrib>Kociok-Köhn, Gabriele</creatorcontrib><creatorcontrib>Marken, Frank</creatorcontrib><title>One-step preparation of the BiVO4 film photoelectrode</title><title>Journal of solid state electrochemistry</title><addtitle>J Solid State Electrochem</addtitle><description>A one-step method of preparing photoelectrochemically active nanostructured BiVO
4
films is reported based on thermolysis (500 °C in air) of a polyethylene glycol (PEG300) “paint-on” precursor solution containing Bi
3+
(as nitrate) and VO
4
3−
(as the metavanadate ammonium salt). Films are formed directly on tin-doped indium oxide (ITO) substrates and characterised by electron microscopy (scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS)), X-ray diffraction, Raman spectroscopy, and photoelectrochemistry. The nanocrystalline film exhibited typically up to 52 % incident photon to current efficiency (IPCE) at 1.0 V vs. saturated calomel electrode (SCE) in aqueous 0.5 M Na
2
SO
4
with oxalate, strongly enhancing photocurrents.
Figure
Coloured FE-SEM image</description><subject>Analytical Chemistry</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Electrochemistry</subject><subject>Energy Storage</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><issn>1432-8488</issn><issn>1433-0768</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9j8tOwzAQRS0EEqXwAezyAwaP7cT2EipeUqVsgK3l2BOaKo0jOyzy96SUNZuZWcy5uoeQW2B3wJi6z8tkmjKQlEtT0vmMrEAKQZmq9PnvzamWWl-Sq5z3jIGqgK1IWQ9I84RjMSYcXXJTF4citsW0w-Kx-6xl0Xb9oRh3cYrYo59SDHhNLlrXZ7z522vy8fz0vnml2_rlbfOwpV4YM1HHeSOdgWCYF8qICpTUJnhUDVQheFka9KHUsmyd58gRQJWNEUFVXroWxZrAKdenmHPC1o6pO7g0W2D26G1P3nbxtkdvOy8MPzF5-R2-MNl9_E7DUvMf6AfS8ltV</recordid><startdate>20150101</startdate><enddate>20150101</enddate><creator>Mascaro, Lucia H.</creator><creator>Pockett, Adam</creator><creator>Mitchels, John M.</creator><creator>Peter, Laurence M.</creator><creator>Cameron, Petra J.</creator><creator>Celorrio, Veronica</creator><creator>Fermin, David J.</creator><creator>Sagu, Jagdeep S.</creator><creator>Wijayantha, K. G. Upul</creator><creator>Kociok-Köhn, Gabriele</creator><creator>Marken, Frank</creator><general>Springer Berlin Heidelberg</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20150101</creationdate><title>One-step preparation of the BiVO4 film photoelectrode</title><author>Mascaro, Lucia H. ; Pockett, Adam ; Mitchels, John M. ; Peter, Laurence M. ; Cameron, Petra J. ; Celorrio, Veronica ; Fermin, David J. ; Sagu, Jagdeep S. ; Wijayantha, K. G. Upul ; Kociok-Köhn, Gabriele ; Marken, Frank</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c399t-a22b4a91d90c3793617489dce7b16ddc459ecd5845fac2e2e1175b93d76c4afe3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Analytical Chemistry</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Electrochemistry</topic><topic>Energy Storage</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mascaro, Lucia H.</creatorcontrib><creatorcontrib>Pockett, Adam</creatorcontrib><creatorcontrib>Mitchels, John M.</creatorcontrib><creatorcontrib>Peter, Laurence M.</creatorcontrib><creatorcontrib>Cameron, Petra J.</creatorcontrib><creatorcontrib>Celorrio, Veronica</creatorcontrib><creatorcontrib>Fermin, David J.</creatorcontrib><creatorcontrib>Sagu, Jagdeep S.</creatorcontrib><creatorcontrib>Wijayantha, K. G. Upul</creatorcontrib><creatorcontrib>Kociok-Köhn, Gabriele</creatorcontrib><creatorcontrib>Marken, Frank</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of solid state electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mascaro, Lucia H.</au><au>Pockett, Adam</au><au>Mitchels, John M.</au><au>Peter, Laurence M.</au><au>Cameron, Petra J.</au><au>Celorrio, Veronica</au><au>Fermin, David J.</au><au>Sagu, Jagdeep S.</au><au>Wijayantha, K. G. Upul</au><au>Kociok-Köhn, Gabriele</au><au>Marken, Frank</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>One-step preparation of the BiVO4 film photoelectrode</atitle><jtitle>Journal of solid state electrochemistry</jtitle><stitle>J Solid State Electrochem</stitle><date>2015-01-01</date><risdate>2015</risdate><volume>19</volume><issue>1</issue><spage>31</spage><epage>35</epage><pages>31-35</pages><issn>1432-8488</issn><eissn>1433-0768</eissn><abstract>A one-step method of preparing photoelectrochemically active nanostructured BiVO
4
films is reported based on thermolysis (500 °C in air) of a polyethylene glycol (PEG300) “paint-on” precursor solution containing Bi
3+
(as nitrate) and VO
4
3−
(as the metavanadate ammonium salt). Films are formed directly on tin-doped indium oxide (ITO) substrates and characterised by electron microscopy (scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS)), X-ray diffraction, Raman spectroscopy, and photoelectrochemistry. The nanocrystalline film exhibited typically up to 52 % incident photon to current efficiency (IPCE) at 1.0 V vs. saturated calomel electrode (SCE) in aqueous 0.5 M Na
2
SO
4
with oxalate, strongly enhancing photocurrents.
Figure
Coloured FE-SEM image</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s10008-014-2495-y</doi><tpages>5</tpages></addata></record> |
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| subjects | Analytical Chemistry Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Condensed Matter Physics Electrochemistry Energy Storage Original Paper Physical Chemistry |
| title | One-step preparation of the BiVO4 film photoelectrode |
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